Safe Use of Chemical Pesticides and Herbicides

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# Section 10: Stability and Reactivity (cont.) ## Section 15: Regulatory Information (non-mandatory) This section identifies the safety, health, and environmental regulations specific for the product that is not indicated anywhere else on the SDS. The information may include: Any national and/or regional regulatory information of the chemical or mixtures (including any OSHA, Department of Transportation, Environmental Protection Agency, or Consumer Product Safety Commission regulations). ## Section 16: Other Information This section indicates when the SDS was prepared or when the last known revision was made. The SDS may also state where the changes have been made to the previous version. You may wish to contact the supplier for an explanation of the changes. Other useful information also may be included here. ## Employer Responsibilities Employers must ensure that the SDSs are readily accessible to employees for all hazardous chemicals in their workplace. This may be done in many ways. For example, employers may keep the SDSs in a binder or on computers as long as the employees have immediate access to the information without leaving their work area when needed and a back-up is available for rapid access to the SDS in the case of a power outage or other emergency. Furthermore, employers may want to designate a person(s) responsible for obtaining and maintaining the SDSs. If the employer does not have an SDS, the employer or designated person(s) should contact the manufacturer to obtain one. ## References OSHA, 29 CFR 1910.1200(g) and Appendix D. United Nations Globally Harmonized System of Classification and Labelling of Chemicals (GHS), third revised edition, United Nations, 2009. These references and other information related to the revised Hazard Communication Standard can be found on OSHA's Hazard Communication Safety and Health Topics page, located at: http://www.osha.gov/dsg/hazcom/index.html. Disclaimer: This brief provides a general overview of…

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# Triethanolamine Revision Date 11-Mar-2022 Explosion Limits Upper 8.5 vol % Lower 1.3 vol % Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge No information available ## Specific Hazards Arising from the Chemical Thermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat and sources of ignition. Hazardous Combustion Products Nitrogen oxides (NOx). Carbon monoxide (CO). Carbon dioxide (CO2). Hydrogen cyanide (hydrocyanic acid). Formaldehyde. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. ## NFPA <table><tr><th>Health</th><th>Flammability</th><th>Instability</th><th>Physical hazards</th></tr><tr><td>2</td><td>1</td><td>1</td><td>N/A</td></tr><tr><td colspan="4">6. Accidental release measures</td></tr><tr><td>Personal Precautions Environmental Precautions</td><td colspan="3">Use personal protective equipment as required. Ensure adequate ventilation. Should not be released into the environment.</td></tr><tr><td colspan="4">Methods for Containment and Clean Sweep up and shovel into suitable containers for disposal. Up</td></tr></table> Up <table><tr><th colspan="2">7. Handling and storage</th></tr><tr><td>Handling</td><td>Wear personal protective equipment/face protection. Ensure adequate ventilation. Avoid contact with skin, eyes or clothing. Avoid ingestion and inhalation.</td></tr><tr><td>Storage.</td><td>Keep containers tightly closed in a dry, cool and well-ventilated place. Keep under nitrogen. Store under an inert atmosphere. Protect from moisture. Incompatible Materials. Strong oxidizing agents. Acids. Metals.</td></tr></table> ## Exposure Guidelines ## 8. Exposure controls / personal protection <table><tr><th>Component</th><th>ACGIH TLV</th><th>OSHA PEL</th><th>NIOSH IDLH</th><th>Mexico OEL (TWA)</th></tr><tr…

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# Section 10: Stability and Reactivity (cont.) ## Section 12: Ecological Information (non-mandatory) This section provides information to evaluate the environmental impact of the chemical(s) if it were released to the environment. The information may include: - Data from toxicity tests performed on aquatic and/or terrestrial organisms, where available (e.g., acute or chronic aquatic toxicity data for fish, algae, crustaceans, and other plants; toxicity data on birds, bees, plants). - Whether there is a potential for the chemical to persist and degrade in the environment either through biodegradation or other processes, such as oxidation or hydrolysis. - Results of tests of bioaccumulation potential, making reference to the octanol-water partition coefficient (Kow) and the bioconcentration factor (BCF), where available. - The potential for a substance to move from the soil to the groundwater (indicate results from adsorption studies or leaching studies). - Other adverse effects (e.g., environmental fate, ozone layer depletion potential, photochemical ozone creation potential, endocrine disrupting potential, and/or global warming potential). ## Section 13: Disposal Considerations (non-mandatory) This section provides guidance on proper disposal practices, recycling or reclamation of the chemical(s) or its container, and safe handling practices. To minimize exposure, this section should also refer the reader to Section 8 (Exposure Controls/Personal Protection) of the SDS. The information may include: - Description of appropriate disposal containers to use. - Recommendations of appropriate disposal methods to employ. - Description of the physical and chemical properties that may affect disposal activities. - Language discouraging sewage disposal. - Any special precautions for landfills or incineration activities. ## Section 14: Transport Information (non-mandatory) This section provides guidance on classification information for shipping and transportin…

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WORKER HEALTH AND SAFETY ⑪FACT SHEET Chemical Storage Guidelines: OSHA Oregon OSHA Flammable Materials FLAMMA and Business Services Department of Consumer LIQUID Many chemicals require special storage to minimize serious risk for personal injury and damage to property and equipment. Safe storage of chemicals begins with the proper identification of chemicals to be stored and their hazards. Safety Data Sheets (SDS) provide basic information specific to that chemical. Some chemicals are more flammable than others, and storage and handling requirements are defined by flash point and boiling point. Storage requirements are also affected by the quantity of chemicals being stored, proximity of other materials, and by whether they are stored indoors or outdoors. ## Flammable liquids The flash point is the lowest temperature at which a liquid can form an ignitable mixture (vapor) with air. Flammable liquids vaporize and form flammable mixtures when containers are left open, leaks or spills occur, or the liquids are heated. Vapor mixed with air can ignite with exposure to a spark or a flame. Flammable liquids form flammable vapors at temperatures below 100° F. Flammable liquids form flammable vapors and have a flash point of less than 200° F. At normal room temperatures, extremely flammable liquids form flammable vapors below 73° F. The handling and use of flammable liquids and their vapors may cause health hazards from ingestion, inhalation, or skin contact. Health effects vary, depending on the particular chemical, the chemical concentration, and route of exposure. Dangers include toxicity, reactivity, instability, or corrosivity of the material. The ability of a chemical to either burn or support burning is a potentially disastrous physical hazard. Combustion byproduct contaminants are also a concern because they are different from those of the original flammable material. Byproducts include fumes, gases, smoke, and dust particles. They can produce toxic effects, …

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## Flammable liquids (cont.) CHEMICAL STORAGE GUIDELINES: FLAMMABLE MATERIALS Inappropriate storage can result in hazardous chemical interactions. Keep flammable materials away from incompatible chemicals. For example, the NIOSH Pocket guide identifies turpentine as incompatible and reactive with strong oxidizers, chlorine, chromic anhydride, stannic chloride, and chromyl chloride. ## Do not store flammables with the following: • Oxidizing agents such as chlorates, nitrates, perchlorates, permanganates, and peroxides. They usually do not combust on their own but provide the oxygen to accelerate the combustion rate of other chemicals. • Corrosive chemicals (acids or bases that destructively attack organic and inorganic material). Common acids include sulfuric acid (battery acid), acetic acid, and nitric acid. Although acetic acid and nitric acid are both acids, they are incompatible. Common alkalis (bases) include ammonium hydroxide, calcium oxide (lime), and sodium hydroxide (lye). - Materials susceptible to spontaneous heating and/or explosions. Hydrogen peroxide contacting combustible material can result in spontaneous combustion. Picric acid can be explosive. ● Substances that react with air or moisture to create heat. Sulfuric acid is a corrosive that reacts violently with water, giving off an irritating and toxic fume. Avoid storing flammables in direct sunlight or near other heat sources; eliminate all sources of ignition. Keep the area dry and cool. Use explosion-proof refrigerators designed for chemical storage when chemicals require extra cool temperatures. Most flammable vapors are heavier than air and settle low. Provide adequate ventilation to prevent the accumulation of large amounts of vapor. ## THE CHEMICAL REACTION - FIRE FUEL OXYGEN FIRE IGNITION SOURCE Store flammable materials in a designated and approved fireproof cabinet or storage rooms as required by 29 CFR 1910.106, Flammable Liquids. Cabinets must be labeled: FLAMMABLE - KEEP FI…

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## Before storing flammables, ask: • Is the inventory of flammables appropriate to the workload? • Are containers closed and stored in appropriate fireproof storage containers, cabinets, or rooms when not in use? • Are approved safety cans in use, and are they in good condition? • Are flammables stored with compatible chemicals? • Are flammable liquids stored in areas where vapors cannot collect and away from electrical motors and other sources of ignition? • Are containers labeled appropriately and expiration dates observed? • Are bonding and grounding provisions in place for transfer of flammables? • Are fire extinguishers available? Note: Fire extinguishers need to be appropriate for the type of chemical fire (e.g., class B for flammables). - Are there established procedures for the cleanup of spills and the disposal of chemicals and cleanup materials? • Does the quantity of in-use or stored liquids outside of flammable-storage cabinets or storage rooms exceed 29 CFR 1910.106 requirements? # CHEMICAL STORAGE GUIDELINES: FLAMMABLE MATERIALS Note that Safety Data Sheets may not cover specifics for safe storage and chemical segregation. To learn more about chemical reactivity between mixed chemicals, consult this detailed information. ## Sources • Handbook of Chemical and Environmental Safety in Schools and Colleges, published by J.B. Lippincott Company • NFPA 30, Flammable and Combustible Liquids Code, 2000 Edition ## More information - 29 CFR 1910.106, Flammable Liquids, rule - OAR 437-002, Hazardous Materials - Federal OSHA, Chemical Reativity Hazards - Federal OSHA, Flammable Liquids Fact Sheet - Oregon OSHA Flammable and Combustible Liquids resource page Visit Oregon OSHA ## Workers Your employer cannot retaliate against you for reporting a workplace health or safety concern or violation. For more information on your rights, visit the Oregon OSHA website. <table><tr><th colspan="5">Table H-12 - Maximum Allowable Size of Containers and P…

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# SHA® BR # Hazard Communication Standard: Safety Data Sheets The Hazard Communication Standard (HCS) (29 CFR 1910.1200(g)), revised in 2012, requires that the chemical manufacturer, distributor, or importer provide Safety Data Sheets (SDSs) (formerly MSDSs or Material Safety Data Sheets) for each hazardous chemical to downstream users to communicate information on these hazards. The information contained in the SDS is largely the same as the MSDS, except now the SDSs are required to be presented in a consistent user-friendly, 16-section format. This brief provides guidance to help workers who handle hazardous chemicals to become familiar with the format and understand the contents of the SDSs. The SDS includes information such as the properties of each chemical; the physical, health, and environmental health hazards; protective measures; and safety precautions for handling, storing, and transporting the chemical. The information contained in the SDS must be in English (although it may be in other languages as well). In addition, OSHA requires that SDS preparers provide specific minimum information as detailed in Appendix D of 29 CFR 1910.1200. The SDS preparers may also include additional information in various section(s). Sections 1 through 8 contain general information about the chemical, identification, hazards, composition, safe handling practices, and emergency control measures (e.g., fire fighting). This information should be helpful to those that need to get the information quickly. Sections 9 through 11 and 16 contain other technical and scientific information, such as physical and chemical properties, stability and reactivity information, toxicological information, exposure control information, and other information including the date of preparation or last revision. The SDS must also state that no applicable information was found when the preparer does not find relevant information for any required element. The SDS must also contain Sections 12 throu…