workplace exposure limits on a qld construction site
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Published by SALUSOn Queensland construction sites, workplace exposure to hazardous substances and airborne contaminants should be managed by identifying each contaminant, comparing likely or measured exposure against the applicable exposure standard, and ensuring exposures are kept as low as reasonably practicable and not above the relevant limit. In practice, this means understanding the three main limit types: an 8-hour time-weighted average (TWA), a short-term exposure limit (STEL), and a ceiling limit. TWA is the average airborne exposure over an 8-hour shift; STEL is a 15-minute exposure that must not be exceeded; and a ceiling limit must not be exceeded at any time. Where a substance has a skin notation, controls must also prevent significant absorption through skin or eye contact, not just inhalation. [3] [3] [3] [3]
For Queensland WHS compliance, the practical regulatory expectation is to conduct a risk assessment before work starts, especially where dusts, fumes, vapours, gases, mists, welding fumes, wood dust, silica, solvents, asphalt fumes, or sewer/utility gases may be generated. The assessment should identify the substance, route of exposure, task duration and frequency, number of workers exposed, whether multiple contaminants are present, whether skin absorption is possible, and whether the work is indoors, enclosed, or poorly ventilated. Safety data sheets should be reviewed because they identify known exposure limits and health hazards, and they help determine whether additional controls or monitoring are needed. [11] [7] [5]
Key contaminants commonly relevant to construction include:
- Respirable crystalline silica from cutting, grinding, drilling, chasing, crushing, demolition, abrasive blasting, tunnelling, and asphalt or concrete work
- Total and respirable nuisance dusts or particulates not otherwise regulated
- Welding fumes and metal fumes
- Wood dusts
- Solvent vapours from coatings, adhesives, fuels, and cleaning agents
- Hydrogen sulfide in sewers, pits, wastewater, asphalt-related work, and other low-lying or confined areas
[16] [1] [2] [2] [8] Respirable crystalline silica deserves special attention on construction sites because it is a major health risk and a frequent compliance issue. Silica is present in common materials such as sand, stone, concrete, brick, and mortar, and respirable dust is generated when these materials are cut, drilled, ground, crushed, or demolished. Exposure can cause silicosis, lung cancer, chronic obstructive pulmonary disease, and kidney disease. A widely recognized silica limit is 50 µg/m³ as an 8-hour TWA, with an action level of 25 µg/m³ triggering assessment and follow-up under the cited silica framework. [16] [16] [16] [6] [6]
Exposure monitoring should be undertaken whenever the risk assessment shows uncertainty about whether workers may be exposed above an exposure standard, when high-dust or high-fume tasks are performed, when controls may not be reliable, after process or material changes, or when workers report symptoms. Personal breathing-zone sampling is the preferred method for assessing inhalation exposure because it best reflects what the worker actually breathes. For silica, representative personal sampling of the highest-exposed workers is the benchmark approach where exposure is not otherwise controlled through a specified method. [14] [14] [10] [9]
A sound monitoring program for Queensland construction should include baseline monitoring for high-risk tasks, repeat monitoring when results are near or above the standard, and reassessment after changes to tools, materials, controls, crew size, or work methods. Workers should be informed of results promptly, and if results exceed the applicable standard, the employer should document and implement corrective actions. Monitoring records, sampling methods, laboratory reports, and decisions about controls should be retained as part of the site WHS documentation. [9] [9] [9] [15] [15]
Control measures should follow the hierarchy of control.
- Eliminate the hazardous process or substitute a lower-emission material, product, or method where possible.
- Use engineering controls first: on-tool water suppression, local exhaust ventilation, vacuum dust extraction, process enclosure, isolation, enclosed cabs, and general mechanical ventilation where needed.
- Apply work-practice and administrative controls: restrict access, sequence dusty work away from others, reduce time in exposure zones, maintain equipment, use competent supervision, and train workers in safe methods.
- Use appropriate housekeeping: wet sweeping or HEPA-filtered vacuuming instead of dry sweeping; avoid compressed air unless dust is effectively captured.
- Use PPE, including respirators, only as a supplement when higher-order controls cannot fully control exposure or while those controls are being installed or maintained.
[5] [12] [15] [15] [9] For silica-generating construction tasks, effective controls include wet methods, integrated water delivery, vacuum dust collection, enclosed cabs for plant, dust suppressants, and restricting access to dusty areas. If a task is performed indoors or in an enclosed area, additional exhaust may be needed to prevent visible dust accumulation. Enclosed cabs should be kept clean, sealed, positively pressurized, and fitted with effective intake filtration. [16] [14] [14] [14] [14]
Respiratory protection is important, but it should not be the primary control unless higher-order controls are not feasible or are insufficient. Respirators should be selected based on the contaminant, concentration, task, and work environment, and used under a formal respiratory protection program including fit testing, training, maintenance, and supervision. On construction sites, respirators are especially relevant for silica tasks, welding, solvent vapours, and emergency or confined-space gas hazards. [7] [15] [10] [13]
Where contaminants can also be absorbed through the skin or eyes, inhalation controls alone are not enough. Suitable gloves, coveralls, eye protection, and protective clothing may be required, particularly for solvents, coatings, fuels, and other chemicals with skin notation or splash/contact risk. PPE must be task-specific, properly fitted, maintained, and supported by worker training. [4] [4] [10]
For mixed exposures, the risk assessment should consider additive effects, especially where several solvents, fumes, or dusts affect the same target organ system or contribute to overall respiratory burden. A practical approach is to calculate combined exposure relative to each applicable limit and treat any result above unity as unacceptable. This is particularly relevant on construction sites where workers may be exposed to silica plus general dust, diesel exhaust, welding fume, or solvent vapours during the same shift. [5] [5] [3]
Examples of exposure values from the supplied sources that illustrate the kinds of limits construction employers may encounter include:
- Total dust: 10 mg/m³ TWA; respirable fraction: 5 mg/m³ TWA
- Welding fumes (total particulate): 5 mg/m³
- Wood dust: 5 mg/m³ TWA for most soft and hard woods; Western red cedar: 2\.5 mg/m³
- Quartz respirable crystalline silica: 50 µg/m³ 8-hour TWA in the silica rule cited; older tables in the sources also show higher legacy values for some silica forms
- Hydrogen sulfide: 10 ppm TWA and 15 ppm over 15 minutes in the cited toolbox source
[1] [2] [2] [2] [6] [8] Hydrogen sulfide and other acute gas hazards require additional precautions on construction sites, especially in pits, trenches, sewers, tanks, shafts, and low-lying areas. Air testing should be completed by a qualified person before entry and repeated as conditions change. If hazardous gas is present, ventilate the area; if it cannot be made safe, use appropriate respiratory protection and emergency arrangements. Very high concentrations can cause rapid unconsciousness and death, so these situations should be treated as high-risk and often as confined-space or emergency-response scenarios. [8] [8] [8] [8] [8]
From a WHS management perspective, Queensland construction employers should document an exposure control plan for significant airborne hazards. For silica and similarly serious contaminants, the plan should describe the tasks creating exposure, the engineering controls and work practices used, respiratory protection requirements, housekeeping methods, and how access to affected areas will be restricted. A competent person should verify that controls are implemented and remain effective, and workers should be trained in hazards, symptoms, monitoring methods, and the correct use and limitations of controls and PPE. [15] [15] [15] [15] [10]
In summary, the safest and most defensible approach on Queensland construction sites is to: identify airborne hazards early, use the applicable exposure standard as the benchmark, assess risk task-by-task, monitor personal exposure where uncertainty or significant risk exists, implement engineering and work-practice controls first, supplement with respiratory and other PPE where needed, communicate results to workers, and review controls whenever conditions change. For high-risk contaminants such as respirable crystalline silica, welding fumes, wood dust, solvent vapours, and hydrogen sulfide, proactive monitoring and tightly managed controls are essential to protect worker health and satisfy WHS duties. [9] [10] [16]
Sources used for this answer
[1] Program Directive: Occupational Exposure to Respirable Crystalline Silica; and Correcting Amendment
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# Occupational Exposure to Respirable Crystalline Silica, Parts 1910, 1915, and 1926; Final Rule; and Other Related Standards (cont.) ## $1910.1053 Respirable Crystalline Silica. (cont.) Federal Register/Vol. 81, No. 58/Friday, March 25, 2016/Rules and Regulations [redacted postal code] the action level in accordance with either the performance option in paragraph (d)(2) or the scheduled this section. monitoring option in paragraph (d)(3) of at or above the action level have (2) Performance option. The employer shall assess the 8-hour TWA exposure for each employee on the basis of any combination of air monitoring data or objective data sufficient to accurately characterize employee exposures to respirable crystalline silica. (3) Scheduled monitoring option. (i) The employer shall perform initial monitoring to assess the 8-hour TWA exposure for each employee on the basis. of one or more personal breathing zone air samples that reflect the exposures of employees on each shift, for each job classification, in each work area. Where several employees perform the same tasks on the same shift and in the same work area, the employer may sample a representative fraction of these employees in order to meet this requirement. In representative sampling, the employer shall sample the employee(s) who are expected to have the highest exposure to respirable crystalline silica. (ii) If initial monitoring indicates that employee exposures are below the action level, the employer may discontinue monitoring for those employees whose exposures are represented by such monitoring. (iii) Where the most recent exposure monitoring indicates that employee exposures are at or above the action level but at or below the PEL, the employer shall repeat such monitoring within six months of the most recent monitoring. (iv) Where the most recent exposure monitoring indicates that employee exposures are above the PEL, the employer shall repeat such monitoring within three months of the mos…
[2] Program Directive: Occupational Exposure to Respirable Crystalline Silica; and Correcting Amendment
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# AUTHORIZATION FOR CRYSTALLINE SILICA OPINION TO EMPLOYER (cont.) ## $1926.1153 Respirable crystalline silica. (cont.) Federal Register/Vol. 81, No. 58/Friday, March 25, 2016/Rules and Regulations [redacted postal code] TABLE 1-SPECIFIED EXPOSURE CONTROL METHODS WHEN WORKING WITH MATERIALS CONTAINING CRYSTALLINE SILICA Continued <table><tr><th rowspan="2">Equipment/task</th><th rowspan="2">Engineering and work practice control methods</th><th colspan="2">Required respiratory protection and minimum assigned protection factor (APF)</th></tr><tr><td><4 hours/shift</td><td>>4 hours/shift</td></tr><tr><td rowspan="3">(xvii) Heavy equipment and utility vehicles used to abrade or frac- ture silica-containing materials (e.g., hoe-ramming, rock ripping) or used during demolition activi- ties involving silica-containing materials. (xviii) Heavy equipment and utility vehicles for tasks such as grad- ing and excavating but not in- cluding: Demolishing, abrading, or fracturing silica-containing ma- terials.</td><td>Operate equipment from within an enclosed cab When employees outside of the cab are engaged in the task, apply water and/or dust suppressants as necessary to minimize dust emissions.</td><td>None None</td><td>None. None.</td></tr><tr><td>Apply water and/or dust suppressants as necessary to minimize dust emissions. OR</td><td>None</td><td>None.</td></tr><tr><td>When the equipment operator is the only employee engaged in the task, operate equipment from within an enclosed cab.</td><td>None</td><td>None.</td></tr></table> (2) When implementing the control measures specified in Table 1, each employer shall: (i) For tasks performed indoors or in enclosed areas, provide a means of exhaust as needed to minimize the accumulation of visible airborne dust; (ii) For tasks performed using wet methods, apply water at flow rates sufficient to minimize release of visible dust; (iii) For measures implemented that include an enclosed cab or booth, ensure that the enclo…
[3] MNOSHA Permissible Exposure Limits
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# SUBPART Z -- TOXIC AND HAZARDOUS SUBSTANCES 1910.1000-AIR CONTAMINANTS (cont.) Substituting this information in the formula, we have: (2 x 150+2 x 75 +4 x 50) ÷ 8 = 81.25 ppm Since 81.25 ppm is less than 100 ppm, the 8-hour time weighted average limit, the exposure is acceptable. (2) (i) in case of a mixture of air contaminants an employer shall compute the equivalent exposure as follows: E = (C₁ + L₁) + (C₁₂ ÷ L₂) + . . . (C ÷ L - Where: - E is the equivalent exposure for the mixture. C is the concentration of a particular contaminant. L is the exposure limit for that substance specified in Subpart Z of 29 CFR part 1910. The value of E shall not exceed unity (1). m (ii) To illustrate the formula prescribed in paragraph (d)(2)(i) of this section, consider the following exposures: <table><tr><th>Substance</th><th>Actual concentration of 8 hour exposure (ppm)</th><th>8 hr. TWA PEL (ppm)</th></tr><tr><td></td><td>500</td><td>1000</td></tr><tr><td>BCD</td><td>45</td><td>200</td></tr><tr><td></td><td>40</td><td>200</td></tr><tr><td colspan="3">Substituting in the formula, we have: m = 500 ÷ 1000 + 45 ÷ 200 + 40 ÷ 200 E = 0.500+ 0.225 +0.200 E = 0.925</td></tr></table> - Since Em is less than unity (1), the exposure combination is within acceptable limits. (e) To achieve compliance with paragraphs (a) through (d) of this section, administrative or engineering controls must first be determined and implemented whenever feasible. When such controls are not feasible to achieve full compliance, protective equipment or any other protective measures shall be used to keep the exposure of employees to air contaminants within the limits prescribed in this section. Any equipment and/or technical measures used for this purpose must be approved for each particular use by a competent industrial hygienist or other technically qualified person. Whenever respirators are used, their use shall comply with § 1910.134. (f) Effective dates. The effective date for the permiss…
[4] MNOSHA Permissible Exposure Limits
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# TABLE Z-1-A, LIMITS FOR AIR CONTAMINANTS Permissible Exposure Limits (cont.) <table><tr><th></th><th colspan="3">TWA</th><th colspan="2">STEL</th><th>CEILING</th><th></th><th></th></tr><tr><td>Substance</td><td>CAS No.</td><td>ppm</td><td>mg/m³</td><td>ppm</td><td>mg/m³</td><td>ppm</td><td>mg/m³</td><td>Skin Designation</td></tr><tr><td>Propylene imine</td><td>75-55-8</td><td>2</td><td>55</td><td></td><td></td><td></td><td></td><td>1</td></tr><tr><td>Propylene oxide</td><td>75-56-9</td><td>20</td><td>50</td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Propyne; see Methyl acetylene</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Pyrethrum Pyridine</td><td>8003-34-7 110-86-1</td><td>5 201</td><td>លោ 5 ថា 15</td><td>1118</td><td>1118</td><td></td><td></td><td></td></tr><tr><td>Quinone</td><td>106-51-4</td><td>0.1</td><td>ចិន 0.4</td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Resorcinol</td><td>108-46-3</td><td>10</td><td>45</td><td>20</td><td></td><td></td><td></td><td></td></tr><tr><td>Rhodium (as Rh), metal fume and insoluble compounds</td><td>7440-16-6</td><td></td><td>0.1</td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Rhodium (as Rh), soluble compounds</td><td>7440-16-6</td><td></td><td>0.001</td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Ronnel</td><td>299-84-3</td><td></td><td>10</td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Rosin core solder pyrolysis products, as formaldehyde</td><td>---</td><td></td><td>0.1</td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Rotenone</td><td>83-79-4</td><td></td><td>5</td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Rouge</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Total dust</td><td></td><td></td><td>10</td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Respirable fraction</td><td></td><td></td><td>5</td><td></td><td></td><td></td><…
[5] Toolbox Talk: Hydrogen Sulfide in Construction
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# HYDROGEN SULFIDE IN CONSTRUCTION CAUTION H₁₂S Date Posted: 10/27/2023 Hydrogen Sulfide (H2S) Hazards in Construction Hydrogen sulfide is prevalent in natural gas and petroleum. As a result, Workers in gas plants, refineries, petrochemical plants, pulp mills, underground mines, sewers, wastewater treatment plants, and asphalt plants are at high risk of exposure. Hydrogen sulfide (H2S) is a colorless, flammable, extremely hazardous gas with a "rotten egg" smell. Some common names for the gas include sewer gas, stink damp, swamp gas, and manure gas. It occurs naturally in crude petroleum, natural gas, and hot springs. In addition, hydrogen sulfide is produced by the bacterial breakdown of organic materials and human and animal wastes (e.g., sewage). ## HOW CAN YOU GET EXPOSED TO H2S IN THE WORKPLACE? Hydrogen sulfide is a mucous membrane and respiratory tract irritant. Immediate or delayed pulmonary edema occurs after exposure to high concentrations. Breathing high levels causes loss of consciousness after one or more breaths and death within a few more breaths. Lower concentrations can result in eye irritation, sore throat and cough, shortness of breath, and lung fluid. Symptoms of acute exposure include nausea, headaches, delirium, disturbed equilibrium, tremors, skin and eye irritation, and convulsions. Inhaling high concentrations can produce rapid unconsciousness and death. You can be exposed to hydrogen sulfide gas primarily by breathing it. However, you also can be exposed to hydrogen sulfide gas through skin and eye contact. According to WAC 296-841-[redacted postal code], the exposure limits of H2S are ten (10) parts per million (PPM) over an 8-hour time-weighted average (TWA) and 15 parts per million (PPM) over a 15-minute exposure period. ## HAZARDS OF H2S EXPOSURE Exposure above the permissible exposure limit (PEL) quickly results in loss of consciousness and potentially death. Long-term exposure to lower levels results in H2S passing the lungs an…
[6] OSHA Fact Sheet - OSHA’s Respirable Crystalline Silica Standard for Construction
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OSHA FactSheet CONTROL SILICA DUST Breathe Easier # OSHA's Respirable Crystalline Silica Standard for Construction Workers who are exposed to respirable crystalline silica dust are at increased risk of developing serious silica-related diseases. OSHA's standard requires employers to take steps to protect workers from exposure to respirable crystalline silica. ## What is Respirable Crystalline Silica? Crystalline silica is a common mineral that is found in construction materials such as sand, stone, concrete, brick, and mortar. When workers cut, grind, drill, or crush materials that contain crystalline silica, very small dust particles are created. These tiny particles (known as "respirable" particles) can travel deep into workers' lungs and cause silicosis, an incurable and sometimes deadly lung disease. Respirable crystalline silica also causes lung cancer, other potentially debilitating respiratory diseases such as chronic obstructive pulmonary disease, and kidney disease. In most cases, these diseases occur after years of exposure to respirable crystalline silica. ## How are Construction Workers Exposed to Respirable Crystalline Silica? Exposure to respirable crystalline silica can occur during common construction tasks, such as using masonry saws, grinders, drills, jackhammers and handheld powered chipping tools; operating vehicle- mounted drilling rigs; milling; operating crushing machines; using heavy equipment for demolition or certain other tasks; and during abrasive blasting and tunneling operations. About two million construction workers are exposed to respirable crystalline silica in over 600,000 workplaces. ## What Does the Standard Require? The standard (29 CFR 1926.1153) requires employers to limit worker exposures to respirable crystalline silica and to take other steps to protect workers. Employers can either use a control method laid out in Table 1 of the construction standard, or they can measure workers' exposure to silica and independen…
[7] Program Directive: Occupational Exposure to Respirable Crystalline Silica; and Correcting Amendment
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# AUTHORIZATION FOR CRYSTALLINE SILICA OPINION TO EMPLOYER (cont.) ## $1926.1153 Respirable crystalline silica. (cont.) [redacted postal code] Federal Register/Vol. 81, No. 58/Friday, March 25, 2016/Rules and Regulations (v) Methods of sample analysis. The employer shall ensure that all samples taken to satisfy the monitoring requirements of paragraph (d)(2) of this section are evaluated by a laboratory that analyzes air samples for respirable crystalline silica in accordance with the procedures in Appendix A to this section. (vi) Employee notification of assessment results. (A) Within five working days after completing an exposure assessment in accordance with paragraph (d)(2) of this section, the employer shall individually notify each affected employee in writing of the results of that assessment or post the results in an appropriate location accessible to all affected employees. (B) Whenever an exposure assessment indicates that employee exposure is above the PEL, the employer shall describe in the written notification the corrective action being taken to reduce employee exposure to or below the PEL. (vii) Observation of monitoring. (A) Where air monitoring is performed to comply with the requirements of this section, the employer shall provide affected employees or their designated representatives an opportunity to observe any monitoring of employee exposure to respirable crystalline silica. (B) When observation of monitoring requires entry into an area where the use of protective clothing or equipment is required for any workplace hazard, the employer shall provide the observer with protective clothing and equipment at no cost and shall ensure that the observer uses such clothing and equipment. (3) Methods of compliance-(i) Engineering and work practice controls. The employer shall use engineering and work practice controls to reduce and maintain employee exposure to respirable crystalline silica to or below the PEL, unless the employer can demonstra…
[8] MNOSHA Permissible Exposure Limits
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# TABLE Z-1-A, LIMITS FOR AIR CONTAMINANTS Permissible Exposure Limits (cont.) <table><tr><th></th><th></th><th colspan="2">TWA</th><th colspan="2">STEL</th><th>CEILING</th><th></th><th></th></tr><tr><td>Substance</td><td>CAS No.</td><td>ppm</td><td>mg/m³</td><td>ppm</td><td>mg/m³</td><td>ppm</td><td>mg/m³</td><td>Skin Designation</td></tr><tr><td>Vanadium fume and</td><td>1314-62-1</td><td></td><td>0.05</td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>respirable dust (as V₂05)</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Vegetable oil mist</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Total dust</td><td></td><td></td><td>15</td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Respirable fraction</td><td></td><td>811</td><td>50</td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Vinyl acetate</td><td>108-05-4</td><td>10</td><td>30</td><td>20</td><td>60</td><td></td><td></td><td></td></tr><tr><td>Vinyl benzene; see Styrene</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Vinyl bromide</td><td>593-60-2</td><td>5</td><td>20 20</td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Vinyl chloride; see 1910.1017</td><td>75-01-4</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Vinyl cyanide; see Acrylonitrile</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Vinyl cyclohexene dioxide</td><td>106-87-6</td><td>10</td><td>60</td><td></td><td></td><td></td><td></td><td>×</td></tr><tr><td>Vinylidene chloride</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>(1,1-Dichloroethylene)</td><td>75-35-4</td><td>1</td><td>4</td><td></td><td></td><td></td><td></td><td></td></tr><tr><td>Vinyl toluene</td><td>[redacted postal code]-15-4</td><td>100</td><td>480</td><td></td><td></td><td></td><td></td><td></td></tr><tr>…
[9] Sakrete - Blacktop Patch
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# Sakrete Blacktop Patch Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. ## SECTION 8: Exposure controls/personal protection ## 8.1. Control parameters <table><tr><th colspan="2">Sakrete Blacktop Patch</th></tr><tr><td colspan="2">No additional information available</td></tr><tr><td colspan="2">Asphalt (8052-42-4)</td></tr><tr><td colspan="2">USA - ACGIH - Occupational Exposure Limits</td></tr><tr><td>ACGIH OEL TWA</td><td>0.5 mg/m3 (fume, inhalable particulate matter)</td></tr><tr><td>ACGIH chemical category</td><td>Not Classifiable as a Human Carcinogen fume, coal tar-free</td></tr><tr><td colspan="2">USA - ACGIH - Biological Exposure Indices</td></tr><tr><td>BEI (BLV)</td><td>2.5 µg/l Parameter: 1-Hydroxypyrene with hydrolysis - Medium: urine - Sampling time: end of shift at end of workweek (background) Parameter: 3-Hydroxybenzo(a)pyrene with hydrolysis - Medium: urine - Sampling time: end of shift at end of workweek (nonquantitative)</td></tr><tr><td colspan="2">Quartz ([redacted postal code]-60-7)</td></tr><tr><td colspan="2">USA - ACGIH - Occupational Exposure Limits</td></tr><tr><td>ACGIH OEL TWA</td><td>0.025 mg/m3 (respirable particulate matter)</td></tr><tr><td>ACGIH chemical category</td><td>Suspected Human Carcinogen</td></tr><tr><td colspan="2">USA - OSHA - Occupational Exposure Limits</td></tr><tr><td>Local name</td><td>Quartz (Total Dust) (Silica: Crystalline)</td></tr><tr><td>OSHA PEL (TWA) [1]</td><td>50 µg/m³ (Respirable crystalline silica)</td></tr><tr><td>Remark (OSHA)</td><td>Table Z-3. For OSHA PEL (TWA) use formula: (30 mg/m3 / (%SiO2+2)) for mg/m3. CAS No. source: eCFR Table Z-1.</td></tr><tr><td>Regulatory reference (US-OSHA)</td><td>OSHA Annotated Table Z-3 Mineral Dusts</td></tr><tr><td>8.2. Appropriate engineering controls</td><td></td></tr></table> Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommend…
[10] Respiratory Protection in the Workplace - A Guide for Employers
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# Respiratory Protection in the Workplace A Guide for Employers Respirators are protective devices-used as a last resort-to reduce workers' harmful exposures to airborne hazards, including oxygen-deficient atmospheres. ## What is a Harmful Exposure? Airborne harmful exposures to your employees can be in the form of: • Dusts, fumes, mists, smoke, vapors or gases that are: ○ In excess of any permissible limit prescribed by T8CCR, section 5155. ○ Of such a nature by inhalation as to result in, or have a probability to result in, injury, illness, disease, impairment or loss of function. . Oxygen-deficient atmospheres, which occur when there is less than 19.5% oxygen present. ## How to Identify Harmful Exposures There can be a number of things to consider when trying to accurately determine what your employees' airborne hazardous contaminant exposures are. The following is a brief overview. ## Factors in Assessing Respiratory Hazards • Identify the respiratory hazards your employees are exposed to and determine what the corresponding Cal/OSHA allowable exposure levels are. A good place to start is the SDS for each of the materials your employees work with. - There may be instances where there are no assigned Cal/OSHA exposure limits, in which case there may be other occupational exposure limits, such as NIOSH RELS ## Some important points to take from section 5155, Airborne Contaminants - These are assigned concentration limits to airborne contaminants that nearly all workers may be exposed to daily during a 40-hour workweek for a working lifetime without adverse effect. Also, because of variation in individual susceptibility, an occasional worker may suffer discomfort or aggravation of a preexisting condition or occupational disease upon exposure to concentrations even below the assigned exposure limits. • Harmful exposure to any substance not listed must be controlled in accordance with T8CCR, section 5141, which may include use of respiratory protec…
[11] OSHA Letter of Interpretation | Enforcement Policy for Respiratory Hazards Not Covered by OSHA Permissible Exposure Limits
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Open source documentSource excerpt
# Occupational Safety and Health Administration (cont.) 2. Administrative and Work Practices Controls. The following work practices should be used to reduce occupational exposure to 1BP during degreasing operations: ■ Evaluation of employee body positioning during the various operations. By observing and evaluating the operator's location during various points in the coating operations, it may be possible to prevent the operator from standing in an area where exposure to fugitive 1BP vapors is likely. This includes consideration for where the fans are located in relation to the employees, as well. ■Revise the coating operation's standard operating procedure to document how often the spray hood requires cleaning, how to effectively conduct the cleaning with less employee exposure, and how much solution is required on a rag to effectively coat the exterior of the parts. ■ Instituting a job rotation schedule for the spray area and activities around the degreaser. Other company employees should be trained on these operations so that employees could rotate in and out during the course of the day. ■ Ensuring appropriate preventative maintenance is conducted on the degreaser and still according to the manufacturer's recommendations. ■ Conducting personal air monitoring on a regular basis to determine employee exposure levels to 1BP, ensuring that personal air samples are taken from the employee's breathing zone. Breathing zone samples provide the best indication of the concentration of contaminants in the air the employee is actually breathing. ■ Ensuring employees immediately and thoroughly wash their skin with soap and flowing water if dermal contact with 1BP occurs. 3. Personal Protective Equipment. - To be effective, personal protective equipment must be individually selected, properly fitted and periodically refitted, conscientiously and properly worn, regularly maintained, and replaced as necessary. In addition, employers must: ■ Perform a revised w…
[12] MNOSHA Permissible Exposure Limits
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Open source documentSource excerpt
# SUBPART Z -- TOXIC AND HAZARDOUS SUBSTANCES 1910.1000-AIR CONTAMINANTS An employee's exposure to any substance listed in Table Z-1-A of this section shall be limited in accordance with the requirements of the following paragraphs of this section. (a) Table Z-1-A. Limits for Air Contaminants (1) & (2) Enforcement of Transitional Limits has expired. See Paragraph (3) for Limits. (3) Limits for Air Contaminants Columns. An employee's exposure to any substance listed in Table Z-1-A shall not exceed the Time Weighted Average (TWA), Short Term Exposure Limit (STEL) and Ceiling Limit specified for that substance in Table Z-1-A. (4) Skin Designation. To prevent or reduce skin absorption, an employee's skin exposure to substances listed in Table Z-1-A with an "X" in the Skin Designation column following the substance name shall be prevented or reduced to the extent necessary in the circumstances through the use of gloves, coveralls, goggles, or other appropriate personal protective equipment, engineering controls or work practices. (5) Definitions. The following definitions are applicable to the Limits for Air Contaminants columns of Table Z- 1-A: (i) Time weighted average (TWA) is the employee's average airborne exposure in any 8-hour work shift of a 40-hour work week which shall not be exceeded. (ii) Short term exposure limit (STEL) is the employee's 15-minute time weighted average exposure which shall not be exceeded at any time during a work day unless another time limit is specified in a parenthetical notation below the limit. If another time period is specified, the time weighted average exposure over that time period shall not be exceeded at any time during the working day. (iii) Ceiling is the employee's exposure which shall not be exceeded during any part of the work day. If instantaneous monitoring is not feasible, then the ceiling shall be assessed as a 15-minute time weighted average exposure which shall not be exceeded at any time over a wor…
[13] Best Practice Engineering Control Guidelines to Control Worker Exposure to Respirable Crystalline Silica during Asphalt Pavement Milling
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Open source documentSource excerpt
# The Silica/Asphalt Milling Machine Partnership (cont.) ## Silica and Health Effects (cont.) defined as amorphous [NIOSH 1974]. The three most common forms of crystalline silica encountered in construction and mining are quartz, tridymite, and cristobalite. NIOSH defines respirable crystalline silica as "that portion of airborne crystalline silica that is capable of entering the gas-exchange regions of the lungs if inhaled; by convention, a particle-size-selective fraction of the total airborne dust; includes particles with aerodynamic diameters less than approximately 10 um and has a 50% deposition efficiency for particles with an aerodynamic diameter of approximately 4 μm" [NIOSH 2002]. NIOSH estimates that at least 1.7 million American workers are exposed to respirable crystalline silica and that many of those workers' exposures exceed current occupational exposure limits [NIOSH 2002]. Inhalation of respirable crystalline silica can cause silicosis, a debilitating and potentially fatal lung disease. Silica exposure has also been associated with lung cancer, chronic obstructive pulmonary disease, renal disease, and other adverse health outcomes [NIOSH 2002]. During the period from 1990 through 1999, at least one-third of decedents with silicosis had worked in construction or mining [NIOSH 2007b]. ## Occupational Exposure Limits In the United States, occupational exposure limits (OELs) have been established by federal agencies, professional organizations, state and local governments, and other entities. The U.S. Department of Labor OSHA permissible exposure limits (PELS) [29 CFR 1910.1000 (2003)] are OELs that are legally enforceable in covered workplaces under the Occupational Safety and Health Act. NIOSH issues RELs that are based on a critical review of the scientific and technical information available on the prevalence of health effects, the existence of safety and health risks, and the adequacy of methods to identify and control hazards [NIOSH 1992]. O…
[14] WAC 296-841-[redacted postal code] - Permissible exposure limits (PELs)
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Open source documentSource excerpt
# WAC 296-841-[redacted postal code] Permissible exposure limits (PELS). IMPORTANT: The following information applies to Table 3, Permissible Expo- sure Limits (PELS) for Airborne Contaminants. (1) Ppm refers to parts of vapor or gas per million parts of air by volume, at 25 degrees C and 760 mm Hg pressure. (2) Mg/m³ refers to milligrams of an airborne contaminant per cu- bic meter of air. (3) F/cc refers to fibers per cubic centimeter of air. (4) For a metal that is measured as the metal itself, only the CAS number for the metal is given. The CAS numbers for individual com- pounds of the metal are not provided. For more information about CAS registry numbers see the website: http://www.cas.org. (5) Short-term exposure limits (STEL) pertain to fifteen-minute exposure periods, unless another time period is noted in Table 3. (6) An "X" in the "skin" column indicates the contaminant can be absorbed through the skin, either by airborne or direct contact. (a) Personal protective equipment (PPE) to prevent skin contact may be needed to minimize the risk for adverse health effects when em- ployees are exposed to these chemicals. (b) Requirements for the use of gloves, coveralls, goggles, and other personal protective equipment can be found in WAC [redacted identifier], Personal protective equipment (PPE). (7) Nuisance dusts (also known as inert dusts) are included in the Table 3 listing, particulates not otherwise regulated (PNOR). - The PNOR listing in Table 3 also applies to other particulate airborne contaminants for which a specific PEL is NOT listed unless the airborne contaminant is found to require a lower limit. (8) The respirable fraction of a particulate airborne contaminant is measured by sampling with a size-selector having the following characteristics: <table><tr><th>Mean aerodynamic diameter in micrometers</th><th>Percent passing the selector</th></tr><tr><td>1</td><td>97</td></tr><tr><td>2</td><td>91</td></tr><tr><td>3</td><td>74</td></tr><t…
[15] OSHA Letter of Interpretation | Enforcement Policy for Respiratory Hazards Not Covered by OSHA Permissible Exposure Limits
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Open source documentSource excerpt
# Occupational Safety and Health Administration (cont.) - However, if the exposed employees were wearing appropriate respiratory protection with no deficiencies in the respirator program, then the likelihood that OSHA could establish a respiratory hazard covered by the general duty clause would be low. b. The hazard was recognized - OSHA can establish this element in one of two ways. (1) For employer recognition: Evidence may include employee complaints to management, illness and injury logs, consultant reports, a previous HAL, internal safety and health policies related to workplace operations involving the chemical that may refer to an OEL, or information from a manufacturer describing safety and health precautions for equipment or chemicals used in the workplace such as the chemical manufacturers' safety data sheet (SDS). (2) For industry recognition: Evidence may include an industry or trade association's guidance document, or an assessment from an industry expert describing the work practice or operation used at the establishment and explaining the particular health hazards and recommended control measures. Alternatively, a similar publication from a (non-OSHA) federal, state, or local government agency, or from a professional organization, may also provide good evidence. Some examples of government agencies include the National Institute for Occupational Safety and Health (NIOSH), the National Toxicology Program (NTP), and the U.S. Environmental Protection Agency (EPA). Examples of organizations include The Center for Construction Research and Training (CPWR, formerly The Center to Protect Workers' Rights), the American Conference of Governmental Industrial Hygienists (ACGIHTM), and the Occupational Alliance for Risk Science (OARS). c. The hazard was causing or was likely to cause death or serious physical harm - Although an illness or injury from the measured exposure need not have occurred yet, the strongest evidence is an employee illness/injury, hospit…
[16] Program Directive: Occupational Exposure to Respirable Crystalline Silica; and Correcting Amendment
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Open source documentSource excerpt
# Occupational Exposure to Respirable Crystalline Silica, Parts 1910, 1915, and 1926; Final Rule; and Other Related Standards (cont.) ## §1910.1000 Air contaminants. (cont.) [redacted postal code] Federal Register/Vol. 81, No. 58/Friday, March 25, 2016/Rules and Regulations TABLE Z-3-MINERAL DUSTS-Continued <table><tr><th></th><th>Substance</th><th></th><th>mppcf a</th><th>mg/m³</th></tr><tr><td>Quartz (Respirable)</td><td></td><td></td><td>250b</td><td>10 mg/m³° % SiO2+2</td></tr><tr><td>Cristobalite: Use 1/2 the value calculated from the Tridymite: Use 1/2 the value calculated from the</td><td>count or formulae for</td><td>mass formulae for quartzf quartz</td><td>%SiO2+5</td><td></td></tr><tr><td></td><td></td><td></td><td></td><td></td></tr></table> a Millions of particles per cubic foot of air, based on impinger samples counted by light-field techniques. b The percentage of crystalline silica in the formula is the amount determined from airborne samples, except in those instances in which other methods have been shown to be applicable. Both concentration and percent quartz for the application of this limit are to be determined from the fraction passing a size-selector with the following characteristics: <table><tr><th></th><th>Aerodynamic diameter (unit density sphere)</th><th>Percent passing selector</th></tr><tr><td>2</td><td></td><td>90</td></tr><tr><td>2.5</td><td></td><td>75</td></tr><tr><td>3.5</td><td></td><td>50</td></tr><tr><td>5.0</td><td></td><td>25</td></tr><tr><td>10</td><td></td><td>0</td></tr></table> 0 The measurements under this note refer to the use of an AEC (now NRC) instrument. The respirable fraction of coal dust is determined with an MRE; the figure corresponding to that of 2.4 mg/m³ in the table for coal dust is 4.5 mg/m³k. 'This standard applies to any operations or sectors for which the respirable crystalline silica standard, 1910.1053, is stayed or is otherwise not in effect. ## ■4. Add § 1910.1053 to read as follows: ## …
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