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Published by SALUS

Toolbox Talk: Safe Work Procedures

Date: [DATE] Duration: [DURATION] minutes Presenter: [PRESENTER NAME] Location: [LOCATION]

Objective

To ensure all employees understand and follow safe work procedures to minimize workplace hazards and prevent incidents.

Introduction

Safe work procedures are essential for maintaining a safe and healthy work environment. They provide a step-by-step guide to performing tasks safely and efficiently. Following these procedures helps reduce the risk of accidents, injuries, and exposure to hazardous materials.

Presenter Note: Engage the audience by asking if anyone has personal experience related to the topic.

Key Points

Understand the Procedure: Before starting any task, thoroughly read and understand the relevant safe work procedure.
Follow the Steps: Adhere to each step of the procedure in the correct order.
Use Required Equipment: Ensure all necessary tools and equipment are available and in good working condition.
Wear Appropriate PPE: Always use the required personal protective equipment (PPE) for the task.
Report Hazards: Immediately report any hazards or unsafe conditions to your supervisor.

Hazard Identification

[Describe common hazards related to the topic]

Exposure to Hazardous Materials: Contact with chemicals can cause skin irritation, respiratory problems, or other health issues [1], [2], [3], [4], [5].
Slips, Trips, and Falls: Wet or cluttered surfaces can lead to falls and injuries [6], [7].
Equipment Malfunctions: Faulty equipment can cause accidents and injuries [8].

Presenter Note: Encourage participants to share any additional hazards they've encountered.

Control Measures

[Discuss the hierarchy of controls: Elimination, Substitution, Engineering Controls, Administrative Controls, Personal Protective Equipment]

Engineering Controls: Use ventilation systems to minimize exposure to airborne contaminants [9], [10].
Administrative Controls: Implement regular safety training and hazard communication programs [11].
Personal Protective Equipment (PPE): Wear appropriate gloves, eye protection, and respiratory protection when handling hazardous materials [6], [12], [13], [14], [15].
Safe Handling Practices: Avoid contact with skin and eyes, and inhalation of vapors and mists [6], [7].

Safe Work Procedures

Review the SDS: Before handling any chemical, review the Safety Data Sheet (SDS) to understand the hazards and necessary precautions [1], [2], [3], [4], [5].
Prepare the Work Area: Ensure the work area is clean, well-ventilated, and free of obstructions [6], [7].
Use Appropriate PPE: Wear the required personal protective equipment, such as gloves, eye protection, and respiratory protection [6], [12], [13], [14], [15].
Follow Equipment Instructions: Operate equipment according to the manufacturer's instructions and safety guidelines [8].
Dispose of Waste Properly: Dispose of chemical waste and contaminated materials according to established procedures [8].

Presenter Note: If possible, demonstrate the safe work procedure or use visual aids.

Personal Protective Equipment (PPE) Requirements

Safety Glasses/Goggles: Protect eyes from chemical splashes and dust [6], [12], [13], [14], [15].
Gloves: Prevent skin contact with hazardous materials; ensure gloves are chemical-resistant and in good condition [6], [12], [13], [14], [15].
Respiratory Protection: Use respirators in areas with poor ventilation or when handling airborne contaminants [12], [15].

[Emphasize the importance of proper PPE use and maintenance]

Real-World Example or Case Study

[Provide a detailed description of a relevant real-world scenario or case study]

[Discuss what went wrong or right, and the lessons learned]

Presenter Note: Ask participants if they can relate this example to their own experiences.

Group Discussion

Discuss the following questions:

What are the most common hazards you encounter in your daily tasks?
How can we improve our adherence to safe work procedures?
What PPE do you find most challenging to use, and how can we address these challenges?

Presenter Note: Encourage active participation and facilitate the discussion.

Emergency Procedures

[Outline the steps to take in case of an emergency related to the topic]

Evacuate: In case of a chemical spill or other emergency, evacuate the area immediately [8].
Report: Report the incident to your supervisor and emergency response team [8].
First Aid: Provide first aid to injured personnel, if trained and safe to do so [7].
Contain: If possible, contain the spill to prevent further spread, using appropriate materials [6], [7].

Questions and Answers

[Encourage participants to ask questions]

[Provide answers to common questions related to the topic]

Q: What should I do if I'm unsure about a step in the safe work procedure?

A: Always ask your supervisor or a qualified colleague for clarification before proceeding.

Q: How often should I inspect my PPE?

A: Inspect your PPE before each use to ensure it is in good condition and fits properly.

Q: What do I do if I have a chemical exposure?

A: Immediately wash the affected area, report the incident, and seek medical attention [1], [2], [3], [4], [5].

Summary

[Recap the main points covered in the toolbox talk]

Safe work procedures are crucial for preventing workplace incidents.
Always understand and follow the correct procedures for each task.
Use the required PPE and ensure it is in good condition.
Report any hazards or unsafe conditions to your supervisor.

Action Items

[List specific actions participants should take following this toolbox talk]

Review relevant safe work procedures for your tasks.
Inspect your PPE and report any deficiencies.
Participate actively in safety training sessions.

Remember: Safety is everyone's responsibility. Follow safe work procedures to protect yourself and your colleagues.

Report all hazards, near-misses, and incidents to your supervisor immediately.

Safety powered by SALUS

15 source record(s)

Sources used for this answer

[1] 3M™ Super 77™ Multipurpose Spray Adhesive

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# 3M(TM) Super 77(TM) Multipurpose Spray Adhesive 10/15/24 (cont.) ## 5.2. Special hazards arising from the substance or mixture (cont.) 3M(TM) Super 77(TM) Multipurpose Spray Adhesive 10/15/24 Hydrocarbons Carbon monoxide Carbon dioxide Hydrogen Fluoride During Combustion During Combustion During Combustion During Combustion ## 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. ## SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-e…

[2] MAPEI - Planiseal VS - Part B

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## 4. FIRST AID MEASURES (cont.) After contact with skin, wash immediately with soap and plenty of water. In case of eyes contact: After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist immediately. Protect uninjured eye. In case of Ingestion: Give nothing to eat or drink. In case of Inhalation: Remove casualty to fresh air and keep warm and at rest. Most important symptoms/effects, acute and delayed Eye irritation Eye damages Skin Irritation Erythema Indication of any immediate medical attention and special treatment needed In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Treatment: (see paragraph 4.1) ## 5. FIRE-FIGHTING MEASURES Extinguishing media Suitable extinguishing media: Water. Carbon dioxide (CO2). Unsuitable extinguishing media: None in particular. Specific hazards arising from the chemical Do not inhale explosion and combustion gases. Burning produces heavy smoke. Hazardous combustion products: N.A. Explosive properties: N.A. Oxidizing properties: N.A. ## Special protective equipment and precautions for fire-fighters Use suitable breathing apparatus. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Move undamaged containers from immediate hazard area if it can be done safely. ## 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. Remove persons to safety. Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Limit leakages with earth or sand. ## Methods and material for containment and cleaning up Suitable material for taking up: absorbing material, organic, sand Retain contaminated washing water and dispose it. ## 7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes, inhalation…

[3] Safety Data Sheet - 2-Methoxyethyl Acetate

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# SECTION 8: Exposure controls/personal protection ## 8.1 Control parameters Ingredients with workplace control parameters <table><tr><th>Component</th><th>CAS-No.</th><th>Value</th><th>Control parameters</th><th>Basis</th></tr><tr><td>2-methoxyethyl acetate</td><td>110-49-6</td><td>TWA</td><td>0.1 ppm</td><td>USA. ACGIH Threshold Limit Values (TLV)</td></tr><tr><td></td><td>Remarks</td><td colspan="3">Danger of cutaneous absorption</td></tr><tr><td></td><td></td><td>TWA</td><td>25 ppm 120 mg/m3</td><td>USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants</td></tr><tr><td colspan="5">Skin designation</td></tr><tr><td></td><td></td><td>TWA</td><td>25 ppm 120 mg/m3</td><td>USA. Table Z-1-A Limits for Air Contaminants (1989 vacated values)</td></tr><tr><td></td><td></td><td>TWA</td><td>0.1 ppm 0.5 mg/m3</td><td>USA. NIOSH Recommended Exposure Limits</td></tr><tr><td></td><td></td><td colspan="3">Potential for dermal absorption</td></tr><tr><td></td><td></td><td>PEL</td><td>5 ppm 24 mg/m3</td><td>California permissible exposure limits for chemical contaminants (Title 8, Article 107)</td></tr><tr><td></td><td></td><td colspan="3">Skin</td></tr></table> Biological occupational exposure limits <table><tr><th>Component</th><th>CAS-No.</th><th>Parameters</th><th>Value</th><th>Biological specimen</th><th>Basis</th></tr><tr><td>2-methoxyethyl acetate</td><td>110-49-6</td><td>2- Methoxyace tic acid</td><td>1mg/g Creatinin e</td><td>Urine</td><td>ACGIH - Biological Exposure Indices (BEI)</td></tr><tr><td></td><td>Remarks</td><td colspan="4">End of shift at end of workweek</td></tr></table> ## 8.2 Exposure controls ## Appropriate engineering controls Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. ## Personal protective equipment ## Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or …

[4] LIQUID NAILS FUZE*IT All Surface Interior & Exterior Adhesive

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# Product code 00382927 Date of issue 3 May [redacted street address]-2000 LIQUID NAILS FUZE*IT ALL SURFACE INTERIOR/EXTERIOR ALL- PURPOSE ADHESIVE GRAY (cont.) ## Indication of immediate medical attention and special treatment needed, if necessary (cont.) Product code 00382927 Date of issue [redacted street address]-2000 LIQUID NAILS FUZE*IT ALL SURFACE INTERIOR/EXTERIOR ALL- PURPOSE ADHESIVE GRAY 20.02 ## Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. See toxicological information (Section 11) ## Section 5. Fire-fighting measures <table><tr><th>Extinguishing media</th><th></th></tr><tr><td>Suitable extinguishing media</td><td>: Use an extinguishing agent suitable for the surrounding fire.</td></tr><tr><td>Unsuitable extinguishing media</td><td>: None known.</td></tr><tr><td>Specific hazards arising from the chemical Hazardous thermal decomposition products</td><td>: Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. : Decomposition products may include the following materials: carbon oxides nitrogen oxides metal oxide/oxides Formaldehyde.</td></tr><tr><td>Special protective actions for fire-fighters</td><td>: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.</td></tr><tr><td>Special protective equipment for fire-fighters</td><td>: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece oper…

[5] Safety Data Sheet - Epoxy Resin

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# Section 5. Fire-fighting measures (cont.) ## Section 8. Exposure controls/personal protection (cont.) Product code WE-71-5702/PL Product name EPOXY RESIN Date of issue 18 July 2024 Version 4 # Section 8. Exposure controls/personal protection Ingredient name poxy Resin Methanesulfonic acid, bismuth(3+) salt (3:1) dibismuth trioxide 1-phenoxypropan-2-ol 4-methylpentan-2-one Exposure limits None. None. None. None. ACGIH TLV (United States, 7/2023). STEL: 75 ppm 15 minutes. TWA: 20 ppm 8 hours. OSHA PEL (United States, 5/2018). TWA: 410 mg/m3 8 hours. TWA: 100 ppm 8 hours. <table><tr><th colspan="4">Key to abbreviations</th></tr><tr><td>A</td><td>= Acceptable Maximum Peak</td><td>S</td><td>= Potential skin absorption</td></tr><tr><td>ACGIH</td><td>= American Conference of Governmental Industrial Hygienists.</td><td>SR</td><td>= Respiratory sensitization</td></tr><tr><td>C</td><td>= Ceiling Limit</td><td>SS</td><td>= Skin sensitization</td></tr><tr><td>F</td><td>= Fume</td><td>STEL</td><td>= Short term Exposure limit values</td></tr><tr><td>IPEL</td><td>= Internal Permissible Exposure Limit</td><td>TD</td><td>= Total dust</td></tr><tr><td>OSHA</td><td>= Occupational Safety and Health Administration.</td><td>TLV</td><td>= Threshold Limit Value</td></tr><tr><td>R</td><td>= Respirable</td><td>TWA</td><td>= Time Weighted Average</td></tr><tr><td>Z</td><td>= OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances</td><td></td><td></td></tr></table> ## Consult local authorities for acceptable exposure limits. Recommended monitoring : Reference should be made to appropriate monitoring standards. Reference to national procedures guidance documents for methods for the determination of hazardous substances will also be required. ## Appropriate engineering controls ## Environmental exposure controls ## Individual protection measures Hygiene measures ## Eye/face protection Skin protection Hand protection Gloves : If user operations generate dust, fume…

[6] Safety Data Sheet - alpha-Methylstyrene

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# alpha-Methylstyrene (cont.) ## Precautionary Statements Prevention (cont.) alpha-Methylstyrene Revision Date 27-Mar-2024 # 3. Composition/Information on Ingredients <table><tr><th>Component</th><th>CAS No</th><th>Weight %</th></tr><tr><td>alfa-Methylstyrene</td><td>98-83-9</td><td>>95</td></tr><tr><td>4-tert-Butyl catechol</td><td>98-29-3</td><td>0.0015</td></tr></table> <table><tr><th>alfa-Methylstyrene 4-tert-Butyl catechol</th><th>98-29-3 0.0015</th></tr><tr><td colspan="2">4. First-aid measures</td></tr><tr><td>General Advice</td><td>If symptoms persist, call a physician.</td></tr><tr><td>Eye Contact</td><td>Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.</td></tr><tr><td>Skin Contact</td><td>Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.</td></tr><tr><td>Inhalation</td><td>Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur. Risk of serious damage to the lungs (by aspiration).</td></tr><tr><td>Ingestion</td><td>Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting. Call a physician or poison control center immediately. If vomiting occurs naturally, have victim lean forward.</td></tr><tr><td>Most important symptoms and effects</td><td>May cause allergic skin reaction. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting: Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing</td></tr><tr><td>Notes to Physician</td><td>Treat symptomatically</td></tr><tr><td colspan="2">5. Fire-fighting measures</td></tr><tr><td>Suitable Extinguishing Media</td><td>Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.</td></tr><tr><td…

[7] Sherwin-Williams - HOTLINE Fast Dry Waterborne Traffic Marking Paint

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# Section 8. Exposure controls/personal protection <table><tr><th></th><th>CAS #</th><th>Exposure limits</th></tr><tr><td>Methanol</td><td>67-56-1</td><td>NOM-010-STPS-2014 (Mexico, 4/2016). Absorbed through skin. TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes.</td></tr></table> Biological exposure indices (United States) <table><tr><th>Ingredient name</th><th>Exposure indices</th></tr><tr><td>Methanol</td><td>ACGIH BEI (United States, 1/2024) BEI: 15 mg/l, methanol [in urine]. Sampling time: end of shift.</td></tr></table> ## Biological exposure indices (Canada) No exposure indices known. ## Biological exposure indices (Mexico) <table><tr><th>Ingredient name</th><th>Exposure indices</th></tr><tr><td>Methanol</td><td>Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 15 mg/L [Basal level. The determinant may be present in the biological sample obtained from subjects who have not been occupationally exposed, at a concentration that could affect the interpretation of the results. These background levels are included in the valu; non-specific. The determinant is nonspecific, since it can be found after exposure to other chemicals.], methane [in urine]. Sampling time: at the end of the work shift.</td></tr></table> ## Appropriate engineering controls Environmental exposure controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters o…

[8] Safety Data Sheet - Magnesium Silicate

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# SAFETY DATA SHEET (cont.) ## Label Elements (cont.) Magnesium silicate, activated Revision Date 28-Mar-2024 ## 3. Composition/Information on Ingredients <table><tr><th>Component</th><th>CAS No</th><th>Weight %</th></tr><tr><td>Magnesium silicate</td><td>1343-88-0</td><td>>95</td></tr></table> ## 4. First-aid measures <table><tr><th>Eye Contact</th><th>Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.</th></tr><tr><td>Skin Contact</td><td>Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur.</td></tr><tr><td>Inhalation</td><td>Remove to fresh air. Get medical attention immediately if symptoms occur.</td></tr><tr><td>Ingestion</td><td>Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.</td></tr><tr><td>Most important symptoms and effects</td><td>None reasonably foreseeable.</td></tr><tr><td>Notes to Physician</td><td>Treat symptomatically</td></tr></table> ## 5. Fire-fighting measures Unsuitable Extinguishing Media No information available Flash Point No information available Method - No information available Autoignition Temperature No information available Explosion Limits Upper No data available Lower No data available Oxidizing Properties Not oxidising Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge No information available Specific Hazards Arising from the Chemical Non-combustible. Hazardous Combustion Products Silicon dioxide. Magnesium oxides. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. ## NFPA <table><tr><th>Health</th><th>Flammability</th><th>Instability</th><th>Physical hazards</th></tr><tr><td>0</td><td>0</td><td>0</td><td>N/A</td></tr><tr><td></td><td colspan="3">6. Accidental …

[9] Safety Data Sheet - 4,4'-Methylenebis(phenyl isocyanate)

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# 4,4'-Methylenebis(phenyl isocyanate) Revision Date 28-Mar-2024 <table><tr><th colspan="2">4. First-aid measures</th></tr><tr><td>General Advice</td><td>If symptoms persist, call a physician.</td></tr><tr><td>Eye Contact</td><td>Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.</td></tr><tr><td>Skin Contact</td><td>Wash off immediately with plenty of water for at least 15 minutes. Get medical attention.</td></tr><tr><td>Inhalation</td><td>Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention.</td></tr><tr><td>Ingestion</td><td>Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.</td></tr><tr><td>Most important symptoms and effects</td><td>May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause allergic skin reaction. Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing</td></tr><tr><td>Notes to Physician</td><td>Treat symptomatically</td></tr><tr><td></td><td>5. Fire-fighting measures</td></tr><tr><td>Suitable Extinguishing Media</td><td>Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.</td></tr><tr><td>Unsuitable Extinguishing Media</td><td>No information available</td></tr><tr><td>Flash Point</td><td>202 °C / 395.6 °F</td></tr><tr><td>Method -</td><td>No information available</td></tr><tr><td>Autoignition Temperature</td><td>600 °C / 1112 °F</td></tr><tr><td>Explosion Limits</td><td></td></tr><tr><td>Upper</td><td>No data available</td></tr><tr><td>Lower</td><td>No data available</td></tr><tr><td>Sensitivity to Mechanical Impact</td><td>No information available</td></tr><tr><td>Sensitivity to Static Discharge</td><td>No information available</td></tr></table> Specific Hazards Arising from the Chemical Keep product and empty container away from h…

[10] Safety Data Sheet - Methanol (Methyl Alcohol)

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# Methanol (cont.) ## 3. Composition/Information on Ingredients (cont.) Methanol Revision Date 02-Apr-2024 <table><tr><th colspan="2">4. First-aid measures</th></tr><tr><td>General Advice</td><td>Immediate medical attention is required. Show this safety data sheet to the doctor in attendance.</td></tr><tr><td>Eye Contact</td><td>Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required.</td></tr><tr><td>Skin Contact</td><td>Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.</td></tr><tr><td>Inhalation</td><td>Remove to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Immediate medical attention is required.</td></tr><tr><td>Ingestion</td><td>Do NOT induce vomiting. Call a physician or poison control center immediately.</td></tr><tr><td>Most important symptoms and effects</td><td>Difficulty in breathing. May cause blindness: Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting</td></tr><tr><td>Notes to Physician</td><td>Treat symptomatically</td></tr><tr><td colspan="2">5. Fire-fighting measures</td></tr><tr><td>Suitable Extinguishing Media</td><td>Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.</td></tr><tr><td>Unsuitable Extinguishing Media</td><td>Water may be ineffective</td></tr><tr><td>Flash Point</td><td>10 °C / 50 °F</td></tr><tr><td>Method</td><td>CC (closed cup) Abel-Pensky (DIN [redacted postal code]) Directive 84/449/EEC, A.9</td></tr><tr><td>Autoignition Temperature</td><td>455 °C / 851 °F</td></tr><tr><td>Explosion Limits</td><td></td></tr><tr><td>Upper</td><td>31.00 vol %</td></t…

[11] MAPEI - Primer WE - Part A

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# Safety Data Sheet PRIMER WE / A (cont.) ## Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. Remove persons to safety. Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Limit leakages with earth or sand. ## Methods and material for containment and cleaning up Suitable material for taking up: absorbing material, organic, sand Retain contaminated washing water and dispose it. ## 7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes, inhalation of vapours and mists. Don't use empty container before they have been cleaned. Before making transfer operations, assure that there aren't any incompatible material residuals in the containers. Contaminated clothing should be changed before entering eating areas. Do not eat or drink while working. See also section 8 for recommended protective equipment. ## Conditions for safe storage, including any incompatibilities Keep away from food, drink and feed. Incompatible materials: None in particular. Instructions as regards storage premises: Adequately ventilated premises. Storage temperature: Not available ## 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Community Occupational Exposure Limits (OEL) <table><tr><th></th><th>OEL Type</th><th>Country</th><th>Occupational Exposure Limit</th></tr><tr><td>CAS: 107-98-2</td><td>ACGIH</td><td></td><td>Long Term: 50 ppm; Short Term: 100 ppm A4 - Not Classifiable as a Human Carcinogen;eye and upper respiratory tract irritation;</td></tr><tr><td></td><td>EU</td><td></td><td>Long Term: 375 mg/m3 - 100 ppm; Short Term: 568 mg/m3 - 150 ppm Behaviour Indicative Possibility of significant uptake through the skin;</td></tr><tr><td></td><td>MAK</td><td>GERMANY</td><td>Long Term: 370 mg/m3 - 100 ppm</td></tr><tr><td></td><td>ACGIH</td><td></td><td>Long Term: 50 ppm; Short Term: 100 ppm A4 - Not Classifiable as a Human Carcinogen;eye and upper resp…

[12] Safety Data Sheet - 4,4'-Diaminodiphenylmethane

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# 4,4'-Diaminodiphenylmethane Revision Date 02-Apr-2024 <table><tr><th colspan="2">4. First-aid measures</th></tr><tr><td>Eye Contact</td><td>Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.</td></tr><tr><td>Skin Contact</td><td>Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Immediate medical attention is required.</td></tr><tr><td>Inhalation</td><td>Remove from exposure, lie down. Remove to fresh air. If not breathing, give artificial respiration. Immediate medical attention is required.</td></tr><tr><td>Ingestion</td><td>Never give anything by mouth to an unconscious person. Drink plenty of water. Induce vomiting, but only if victim is fully conscious. Call a physician immediately. Clean mouth with water.</td></tr><tr><td>Most important symptoms and effects</td><td>May cause allergic skin reaction. Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing</td></tr><tr><td>Notes to Physician</td><td>Treat symptomatically</td></tr><tr><td colspan="2">5. Fire-fighting measures</td></tr><tr><td>Suitable Extinguishing Media</td><td>Water spray. Carbon dioxide (CO2). Dry chemical. Chemical foam.</td></tr><tr><td>Unsuitable Extinguishing Media</td><td>No information available</td></tr><tr><td>Flash Point</td><td>221 °C / 429.8 °F</td></tr><tr><td>Method</td><td>No information available</td></tr><tr><td>Autoignition Temperature Explosion Limits</td><td>No information available</td></tr><tr><td>Upper</td><td>No data available</td></tr><tr><td>Lower</td><td>No data available</td></tr><tr><td>Sensitivity to Mechanical Impact Sensitivity to Static Discharge</td><td>No information available No information available</td></tr><tr><td colspan="2">Specific Hazards Arising from the Chemical Keep product and empty container away from heat and …

[13] Safety Data Sheet - Magnesium Silicate

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# Magnesium silicate, activated Revision Date 28-Mar-2024 Methods for Containment and Clean Sweep up and shovel into suitable containers for disposal. Avoid dust formation. Up <table><tr><th colspan="2">7. Handling and storage</th></tr><tr><td>Handling</td><td>Wear personal protective equipment/face protection. Ensure adequate ventilation. Avoid contact with skin, eyes or clothing. Avoid ingestion and inhalation. Avoid dust formation.</td></tr><tr><td>Storage.</td><td>Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible Materials. Strong oxidizing agents. Strong acids.</td></tr><tr><td colspan="2">8. Exposure controls I personal protection</td></tr><tr><td>Exposure Guidelines</td><td>This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies.</td></tr><tr><td>Engineering Measures</td><td>None under normal use conditions.</td></tr><tr><td>Personal Protective Equipment</td><td></td></tr><tr><td>Eye/face Protection</td><td>Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.</td></tr><tr><td>Skin and body protection</td><td>Wear appropriate protective gloves and clothing to prevent skin exposure.</td></tr><tr><td>Respiratory Protection</td><td>No protective equipment is needed under normal use conditions.</td></tr><tr><td>Recommended Filter type:</td><td>Particle filter.</td></tr><tr><td>Hygiene Measures</td><td>Handle in accordance with good industrial hygiene and safety practice.</td></tr></table> <table><tr><th colspan="2">9. Physical and chemical properties</th></tr><tr><td>Physical State</td><td>Powder Solid</td></tr><tr><td>Appearance</td><td>Off-white</td></tr><tr><td>Odor</td><td>No information available</td></tr><tr><td>Odor Threshold</td><td>No information available</td></tr><tr><td>pH</td><td>No information available</td></tr…

[14] Safety Data Sheet - 4,4'-Methylenebis(phenyl isocyanate)

Page 4

Open source document

Source excerpt

# 4,4'-Methylenebis(phenyl isocyanate) Revision Date 28-Mar-2024 Methods for Containment and Clean Sweep up and shovel into suitable containers for disposal. Keep in suitable, closed Up containers for disposal. <table><tr><th colspan="2">7. Handling and storage</th></tr><tr><td>Handling</td><td>Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Ensure adequate ventilation. Avoid dust formation.</td></tr><tr><td>Storage.</td><td>Keep containers tightly closed in a dry, cool and well-ventilated place. To maintain product quality: Keep refrigerated. Incompatible Materials. Strong oxidizing agents. Acids. Bases. Alcohols. Amines. copper. Copper alloys. Water.</td></tr></table> ## 8. Exposure controls I personal protection ## Exposure Guidelines <table><tr><th>Component</th><th>ACGIH TLV</th><th>OSHA PEL</th><th>NIOSH</th><th>Mexico OEL (TWA)</th></tr><tr><td>Methylene bisphenol isocyanate (MDI)</td><td>TWA: 0.005 ppm</td><td>Ceiling: 0.02 ppm Ceiling: 0.2 mg/m3 (Vacated) Ceiling: 0.02 ppm (Vacated) Ceiling: 0.2 mg/m3</td><td>IDLH: 75 mg/m3 TWA: 0.005 ppm TWA: 0.05 mg/m3 Ceiling: 0.020 ppm Ceiling: 0.2 mg/m3</td><td>TWA: 0.005 ppm</td></tr></table> ## Legend ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration NIOSH: NIOSH - National Institute for Occupational Safety and Health <table><tr><th>Engineering Measures</th><th>Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location.</th></tr><tr><td>Personal Protective Equipment</td><td></td></tr><tr><td>Eye/face Protection</td><td>Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Tight sealing safety goggles.</td></tr><tr><td>Skin and body protection</td><td>Wear appropriate protective glov…

[15] Safety Data Sheet - Epoxy Resin

Page 7

Open source document

Source excerpt

# Section 8. Exposure controls/personal protection (cont.) ## Eye/face protection Skin protection Hand protection (cont.) Product code WE-71-5702/PL Product name EPOXY RESIN Date of issue 18 July 2024 Version 4 ## Section 8. Exposure controls/personal protection <table><tr><th>Body protection</th><th>: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.</th></tr><tr><td>Other skin protection</td><td>: Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.</td></tr><tr><td>Respiratory protection</td><td>: Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. The respiratory protection shall be in accordance to 29 CFR 1910.134.</td></tr></table> ## Section 9. Physical and chemical properties <table><tr><th>Appearance</th><th></th></tr><tr><td>Physical state</td><td>: Liquid.</td></tr><tr><td>Color</td><td>: Not available.</td></tr><tr><td>Odor</td><td>: Not available.</td></tr><tr><td>Odor threshold</td><td>: Not available.</td></tr><tr><td>pH</td><td>: Not available.</td></tr><tr><td>Melting point</td><td>: Not available.</td></tr><tr><td>Boiling point</td><td>: >37.78°C (>100°F)</td></tr><tr><td>Flash point</td><td>: Closed cup: 93.89°C (201°F)</td></tr><tr><td>Auto-ignition temperature</td><td>: Not available.</td></tr><tr><td>Decomposition temperature</td><td>: Not available.</td></tr><tr><td>Flammabilit…

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Original answer: Jul 1, 2025

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