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Write a risk assessment for Aspirin content back titration

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A suitable risk assessment and laboratory safety procedure for aspirin determination by back titration should treat the work as a corrosive chemical handling task with splash, inhalation, glassware, and spill hazards. Before starting, complete a task-specific COSHH/PPE hazard assessment, review the SDS for all reagents, confirm the concentrations and volumes to be used, and ensure the SOP defines the titration steps, emergency actions, spill categories, waste routes, and who is authorized to respond to incidents. Hazard assessment should be documented and re-evaluated when chemicals, equipment, or methods change. [7] [8] [4]

Chemical hazard identification and COSHH assessment:

  • Aspirin samples are generally low-volatility solids, but the analytical reagents used for back titration present the main hazards.
  • Hydrochloric acid is corrosive and has an airborne exposure limit; splashes and acid mist are key concerns.
  • Sodium hydroxide is strongly corrosive and can cause severe eye and skin damage; pellets or concentrated solutions also generate heat on dilution.
  • Indicators are typically used in drop quantities, but many are prepared in alcohol or other solvents, so check the SDS for flammability and irritation hazards before use.
  • The COSHH assessment should consider concentration, volume, route of exposure, incompatibilities, heat generation during dilution, likelihood of splashing during burette/pipette work, and waste compatibility.

[9] [15] [16] Handling of acids and bases:

  • Prepare and dispense acids and alkalis carefully, using the minimum practical quantity for the analysis.
  • When making solutions or dilutions, add acid to water and add base to water, never the reverse, to reduce violent heat release and splashing.
  • Use pipette fillers only; never pipette by mouth.
  • Carry reagent bottles with secure caps, keep them below eye level when pouring, and use secondary containment where practical.
  • Neutralize only if your SOP specifically permits it and compatibility is confirmed; otherwise collect as hazardous waste.
  • If acid or alkali contacts skin or eyes, flush immediately with copious water for at least 15 minutes and seek assistance per local emergency procedure.

[12] [12] [12] [12] PPE requirements:

  • Minimum PPE: lab coat, chemical splash goggles or safety goggles, suitable chemical-resistant gloves, long trousers, and closed-toe shoes.
  • Use chemical splash goggles for titration work involving corrosives; add a face shield if there is elevated splash risk during bulk dispensing or dilution.
  • For gloves, select chemical-resistant gloves compatible with the exact reagent concentration and contact time. Nitrile, neoprene, butyl, or natural rubber may be suitable depending on the chemical and concentration.
  • Use an apron or chemical-resistant coat if handling larger volumes of corrosives.
  • Replace contaminated gloves immediately and wash hands after removing PPE.

[10] [3] [16] [14] Exposure controls:

  • Apply the hierarchy of controls: first reduce risk by procedure design, small-scale working, training, and suitable equipment; then use PPE as the final layer.
  • Carry out reagent preparation, dilution, and any work likely to generate acid fumes or solvent vapors in a chemical fume hood or with effective local exhaust ventilation.
  • Keep eyewash and safety shower access unobstructed and close to the work area.
  • Use only the quantities needed for the titration, keep containers closed when not in use, and label all prepared solutions clearly with identity and concentration.
  • Do not eat, drink, or store food in the laboratory; wash hands and face after handling reagents.

[2] [13] [15] Spill response:

  • Your SOP should define what counts as a small spill versus a large spill and who may respond.
  • Only trained personnel with the correct PPE and spill materials should clean up a chemical spill.
  • Alert others, isolate the area, and if the spill is beyond your training or control, evacuate and call for help.
  • If safe, stop the source, remove ignition sources where relevant, and contain the spill with suitable absorbent or neutralizing material.
  • For personal contamination, remove contaminated clothing immediately; use the emergency shower for skin exposure and flush eyes at the eyewash for at least 15 minutes.
  • Collect cleanup residues, contaminated absorbents, and broken glass into properly labeled hazardous waste containers.

[6] [1] [1] [1] Waste disposal:

  • Collect acidic and alkaline titration wastes in compatible, labeled waste containers unless your local procedure explicitly allows controlled neutralization and drain disposal.
  • Do not mix incompatible wastes, and do not dispose of concentrated acids, bases, or indicator solutions to drain unless authorized by local rules.
  • Keep waste containers closed except when adding waste, and segregate glass sharps from liquid chemical waste.
  • Dispose of contaminated absorbents, gloves, and cleanup materials according to local hazardous waste and environmental requirements.

[6] [13] [1] Safe use of glassware, burettes, pipettes, and indicators:

  • Inspect burettes, pipettes, flasks, and funnels for cracks, chips, blocked taps, and damaged tips before use.
  • Clamp burettes securely, fill below eye level where possible, and remove the funnel before titration to avoid drips and overfilling.
  • Use pipette fillers; never use mouth suction.
  • Handle glassware carefully when inserting into stoppers; lubricate if appropriate and protect hands from breakage.
  • Because the task involves working with glass and splash hazards, eye protection and suitable gloves should be part of the assessed controls.
  • Use only the minimum indicator volume needed; avoid skin contact and inhalation, and keep indicator bottles closed when not in use.

[5] [8] [11] Compliance with laboratory safety regulations and SOPs:

  • Maintain a written risk assessment/COSHH assessment and PPE hazard assessment for the aspirin back-titration method.
  • Ensure workers are trained in reagent hazards, titration technique, spill response, eyewash/shower use, waste segregation, and emergency reporting.
  • Keep SDSs accessible for aspirin, sodium hydroxide, hydrochloric acid, and any indicator or solvent used.
  • Follow the laboratory SOP exactly for reagent concentrations, standardization, endpoint recognition, and waste handling; deviations should require supervisor approval.
  • Use engineering and administrative controls before relying on PPE alone, and review the assessment whenever the method, scale, or chemicals change.

[7] [8] [4] In practice, the experiment should only proceed when the analyst has confirmed: correct reagent labeling and concentration, intact glassware, suitable PPE in place, access to eyewash/shower and spill kit, ventilation appropriate to the reagents, a defined waste container, and an approved SOP/COSHH assessment. For routine aspirin back titration at teaching-lab scale, the residual risk is typically low to moderate when small volumes are used and the above controls are implemented consistently; it becomes high if concentrated corrosives are handled without splash protection, ventilation, training, or spill arrangements. [7] [1] [10]

16 source record(s)

Sources used for this answer

[1] Safety Data Sheet - Polymaleic Acid

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# AK Scientific, Inc. Safety Data Sheet (United States) Polymaleic acid Page 3 of 5 container when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from sources of ignition. ,Store long-term in a cool, dry place. ## 8. Exposure Controls/Personal Protection ## Exposure limits: OSHA PEL: Not available. NIOSH REL: Not available. ACGIH TLV: Not available. Appropriate engineering controls: Avoid contact with skin, eyes, and clothing. Wash hands before breaks and immediately after handling the product. Facilities storing or utilizing this material should be equipped with an eyewash fountain. Use adequate general and local exhaust ventilation to keep airborne concentrations low. ## Personal protection Eyes: Based on an evaluation of the eye or face hazards present, wear chemical splash-resistant safety glasses or goggles with side protection. A face shield may be appropriate in some workplaces. Use eyewear tested and approved under appropriate government standards such as OSHA 29 CFR 1910.133 or EU EN166. Hands: Wear gloves selected based on an evaluation of the possible hazards to hands and skin, the duration of use, the physical conditions of the workplace, and the chemical resistance and physical properties of the glove material. Skin and body: Protective clothing must be selected based on the hazards present in the workplace, the physical environment, the duration of exposure, and other factors. No fabric can provide protection against all potential hazards; therefore it is important to select the appropriate protective clothing for each specific hazard. At the minimum, wear a laboratory coat and close-toed footwear. Respiratory: Respirators are not a substitute for accepted engineering control measures such as enclosure or confinement of the operation, general and local ventilation, and substitution of less toxic materials. When respiratory personal protective equipment is appropriate based on an assessmen

[2] Occupational Safety and Health Standards (OSHA 29 CFR 1910) - 1910.1048 App B - Sampling strategy and analytical methods for formaldehyde

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# 3.5 Analysis: (cont.) ## 4. Backup Data (cont.) Place 50 mL of 0.1 M sodium sulfite and three drops of thymophthalein indicator into a 250-mL Erlenmeyer flask. Titrate the contents of the flask to a colorless endpoint with 0.1 N HCl (usually one or two drops is sufficient). Transfer 10 mL of the formaldehyde/methanol solution (prepared in 3.3.1) into the same flask and titrate the mixture with 0.1 N HCl, again, to a colorless endpoint. The formaldehyde concentration of the standard may be calculated by the following equation: Formaldehyde, mg/mL = ## acid titer X acid normality X 30.0 mL of sample This method is based on the quantitative liberation of sodium hydroxide when formaldehyde reacts with sodium sulfite to form the formaldehyde-bisulfite addition product. The volume of sample may be varied depending on the formaldehyde content but the solution to be titrated must contain excess sodium sulfite. Formaldehyde solutions containing substantial amounts of acid or base must be neutralized before analysis. Scroll to Top + OSHA Standards Enforcement Topics Media Center Contact Us UNITED OF LABOR UNITED STATES OF AMERICA U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration [redacted street address] NW Washington, DC [redacted postal code] 1-800-321-OSHA 1-[redacted phone] www.osha.gov FEDERAL GOVERNMENTH White House OCCUPATIONAL SAFETY & HEALTH - Benefits.gov Frequently Asked Questions A- Z Index Submit Feedback

[3] Safety Data Sheet - Hydrochloric Acid

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# SAFETY DATA SHEET (cont.) ## SECTION 8: Exposure controls/personal protection (cont.) <table><tr><th>Component</th><th>CAS-No.</th><th>Value</th><th>Control parameters</th><th>Basis</th></tr><tr><td>Hydrochloric Acid</td><td>7647-01-0</td><td>C</td><td>2 ppm</td><td>USA. ACGIH Threshold Limit Values</td></tr><tr><td></td><td>Remarks</td><td colspan="3">(TLV) Not classifiable as a human carcinogen</td></tr><tr><td></td><td></td><td>C</td><td>5 ppm 7 mg/m3</td><td>USA. NIOSH Recommended Exposure Limits</td></tr><tr><td></td><td></td><td>C</td><td>5 ppm 7 mg/m3</td><td>USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants</td></tr><tr><td></td><td></td><td>PEL</td><td>0.3 ppm 0.45 mg/m3</td><td>California permissible exposure limits for chemical contaminants (Title 8, Article 107)</td></tr><tr><td></td><td></td><td>C</td><td>2 ppm</td><td>California permissible exposure limits for chemical contaminants (Title 8, Article 107)</td></tr></table> ## 8.2 Exposure controls Appropriate engineering controls Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. ## Personal protective equipment ## Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles ## Skin protection This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN [redacted postal code]-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-[redacted postal code] Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested: KCL 741 Dermatril® L This recommendation applies only to the product stated in the safety data

[4] Rules for the Administration of the Oregon Safe Employment Act (General Occupational Safety and Health, Division 2, OSHA Oregon)

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# NONMANDATORY PROTOCOL FOR BIOLOGICAL MONITORING (cont.) ## 2.7. Safety precautions (cont.) Oregon Administrative Rules Oregon Occupational Safety and Health Division # NONMANDATORY PROTOCOL FOR BIOLOGICAL MONITORING Z 2.7.3. Wear gloves, lab coat, and safety glasses while handling all human urine products. Disposable plastic, glass, and paper (pipet tips, gloves, etc.) that contact urine should be placed in a biohazard autoclave bag. These bags should be kept in appropriate containers until sealed and autoclaved. Wipe down all work surfaces with 10% sodium hypochlorite solution when work is finished. 2.7.4. Dispose of all biological samples and diluted specimens in a biohazard autoclave bag at the end of the analytical run. 2.7.5. Special care should be taken when handling and dispensing nitric acid. Always remember to add acid to water (or urine). Nitric acid is a corrosive chemical capable of severe eye and skin damage. Wear metal-free gloves, a lab coat, and safety glasses. If the nitric acid comes in contact with any part of the body, quickly wash with copious quantities of water for at least 15 minutes. 2.7.6. Special care should be taken when handling and dispensing NaOH. Always remember to add base to water (or urine). NaOH can cause severe eye and skin damage. Always wear the appropriate gloves, a lab coat, and safety glasses. If the NaOH comes in contact with any part of the body, quickly wash with copious quantities of water for at least 15 minutes. 3. Analytical Procedure 3.1. Apparatus 3.1.1. A high performance liquid chromatograph equipped with pump, sample injector and UV detector. 3.1.2. A C18 HPLC column; 25 cm X 4.6 mm I.D. 3.1.3. An electronic integrator, or some other suitable means of determining analyte response. 3.1.4. Stripchart recorder. 3.1.5. C18 SEP-PAKs (Waters Associates) or equivalent. 3.1.6. Luer-lock syringe for sample preparation (5 mL or 10 mL). 3.1.7. Volumetric pipettes and flasks for stan

[5] Chemical Hazard Communication: Training course for employees

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# Corrosive chemicals - Corrosive chemicals cause chemical burns to the eyes, skin and the lungs if inhaled. - They include acids and caustics (bases). - The extent of harm depends on how concentrated the corrosive is and if the corrosive can be washed out of the eyes. or off the skin immediately. Sodium Hydroxide Pellets NaOH M.Wt 40.00 g/mol Quality Reagent Cha Risk Phrase Hydrochloric acid 37% Imitating to respiratory sy Causes buns Safety Phrase In case of contact whees me mas plenty of water and sek nedol de Wear suitable protective dig pen protection In case of accident or you d HCI M.Wt 36.46 g/mol advice immediately (how he a For laboratory and mantic 数 not for drug food and Washington State Department of Labor & Industries 27

[6] Sodium Hydroxide

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# What are the engineering controls for sodium hydroxide? Engineering Controls: Use a local exhaust ventilation and enclosure, if necessary, to control amount in the air. It may be necessary to use stringent control measures such as process enclosure to prevent product release into the workplace. Use a corrosion-resistant exhaust ventilation system separate from other ventilation systems. Exhaust directly to the outside, taking any necessary precautions for environmental protection. ## What Personal Protective Equipment (PPE) is needed when working with sodium hydroxide? Eye/Face Protection: Wear chemical safety goggles. A face shield (with safety goggles) may also be necessary. Skin Protection: Wear chemical protective clothing e.g. gloves, aprons, boots. Suitable materials (sodium hydroxide 30-70%) include: butyl rubber, natural rubber, neoprene rubber, nitrile rubber, polyvinyl chloride (PVC), Viton, Viton®/butyl rubber, AlphaTec® (02-100, 4000, EVO, VPS), Kemblok®, Barrier® - PE/PA/PE, Silver Shield® - PE/EVAL/PE, Trellchem® HPS, Trellchem® VPS, Saranex®ᵀM, Chemprotex® 300, ChemMAX® (3), Frontline® 500, Tychem® BR/LV, Tychem® (5000, 6000, 6000 FR, 9000, Responder® CSM, [redacted postal code], [redacted postal code] FR), Zytron® (300, 500), Recommendations are NOT valid for very thin natural rubber, neoprene rubber, nitrile rubber, and PVC gloves (0.3 mm or less). ## Respiratory Protection: Up to 10 mg/m³: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode*; OR Any powered air-purifying respirator with a high-efficiency particulate filter*. (APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter; OR Any self-contained breathing apparatus with a full facepiece; OR Any supplied-air respirator with a full facepiece. *Causes eye irritation or damage; eye protection needed. APF = Assigned Protection Factor Recommendations apply only to National Institute for Occupational Safety and Health (NIOSH) appro

[7] Spill Response - Chemicals

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# Spill Response - Chemicals (cont.) ## How can a workplace prepare for a chemical spill response? (cont.) American Society for Testing and Materials (ASTM) Standard Guide for Using Aqueous Foams to Control the Vapor Hazard from Immiscible Volatile Liquids (USA) ## What should a chemical spill control procedure include? A spill control procedure should define and establish the following: - Definition of what that workplace considers to be small and large spills, including the types of spills that can be handled internally versus the spills that a specialized spill response team should handle. Generally speaking: - A small spill is one that is of a limited quantity, does not spread fast, and does not place workers, the workplace, or the environment in danger. - A specialized spill response should be used where there is a risk of fire or explosion or the chemical is highly toxic. - Who is to respond to the spill and their contact information - Spill prevention measures to be followed. These measures may include using double-wall tanks, secondary containment, and following safe handling and storing procedures. - Instructions on how to control spills of specific chemicals, and when safe to do so. - The appropriate method to reduce the hazard of the spilled chemical (e.g., stabilization, neutralization, dilution, etc.). - Clean-up procedures. - Area decontamination procedures. - How to dispose of the contaminated materials. These materials should be disposed of according to local regulatory requirements for environmental protection. - First aid procedures. - List of appropriate personal protective equipment (PPE) - Decontamination procedures for the personal protective equipment (PPE), as appropriate - Reporting procedures for all spills and near-misses, such as to a specified person or department, or the health and safety committee. - Determine which spills must be reported to local authorities, especially if the spill has leaked into the drains or

[8] Spill Response - Chemicals

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CCOHS CCHST Canadian Centre for Occupational Health and Safety Centre canadien d'hygiène et de sécurité au travail # Chemicals and Materials # Spill Response - Chemicals ## How can a workplace prepare for a chemical spill response? Most workplaces have products that are used and stored on their premises. Some may have a small amount (only a few litres of cleaning products, for example), while others may have significant quantities of chemicals in different physical forms. Each of these workplaces should develop and implement measures appropriate for the chemicals and quantity present. - Perform and maintain an accurate inventory of all chemicals in your workplace. - Use the information provided in safety data sheets (SDSs) and other technical data to identify the hazardous properties of the chemicals (e.g., flammable, corrosive, oxidant, reactivity with water, air toxicity). - Conduct a risk assessment. Identify the amount or size of the potential spills and the potential and severity to workers' health, the workplace, and the environment. - Based on the chemical's physical state (e.g., liquid or solid, including powders), determine the best methods to prevent, control, stabilize, and clean that spill. - Identify the materials, equipment, and personal protective equipment needed. The respiratory protection and protective clothing must be compatible with the chemical. Not all personal protective equipment will be compatible with all chemicals. - Develop a spill control procedure. - Make a spill response kit that contains chemical- or process-specific materials, the corresponding personal protective equipment, and other needed equipment. Make sure the kits are available near the work area and well-stocked at all times. - Train the workers to know the hazards of the chemicals they work with and how to respond to a spill. - Establish a spill response team as needed. Some useful standards to consult when developing a spill response plan include: - Nation

[9] PPE Hazard Assessment Certification Form

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# PPE Hazard Assessment Certification Form (cont.) ## EYES (cont.) [ ] grinding [ ] sawing [ ] hammering [ ] working with glass [ ] using power tools [ ] tools or materials that could scrape, bruise, or cut [ ] extreme heat [ ] extreme cold [ ] animal bites [ ] electric shock [ ] vibration [ ] musculoskeletal disorders [ ] sharps injury [ ] other: If no, use: [ ] Gloves [ ] Chemical resistance [ ] Liquid/leak resistance [ ] Temperature resistance [ ] Abrasion/cut resistance [ ] Slip resistance [ ] Latex or nitrile [ ] Anti-vibration [ ] Protective sleeves [ ] Ergonomic equipment: <empty> [ ] Other: <empty> FEET/LEGGS Work activities such as: [ ] use of corrosive or flammable materials [x] other: Work-related exposure to: [ ] explosive atmospheres [ ] explosives [ ] crushing [ ] sharps injury [ ] blood [ ] chemical splash [ ] chemical penetration [ ] extreme heat/cold [ ] other: Can hazard be eliminated without the use of PPE?: Yes [ ] No If no, use: [ ] Safety shoes or boots [ ] Toe protection [ ] Metatarsal protection [ ] Electrical protection [ ] Puncture resistance [ ] Anti-slip soles [ ] Leggings or chaps [ ] Foot-Leg guards [ ] Other: <empty> BODY/SKIN & BODY/ WHOLE Work activities such as: [ ] use of corrosive or flammable chemicals [ ] other: Work-related exposure to: [ ] chemical splashes [ ] extreme heat [ ] extreme cold [ ] sharp or rough edges [ ] irritating chemicals [ ] other: Can hazard be eliminated without the use of PPE?: Yes [ ] No If no, use: [ ] Vest, Jacket [ ] Flame resistant jacket/pants [ ] Coveralls, Body suit [ ] Raingear [ ] Apron [ ] Abrasion/cut resistance With: [ ] Long or full sleeves [ ] Hood

[10] Personal Protective Equipment (PPE) Guide

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# Option 2 SAMPLE 2 Job Hazard Analysis for Personal Protective Equipment (PPE) Assessment Job/task: Lathe operator Location: Lathe room <table><tr><th>Job/Task Step</th><th>Hazard Type</th><th>Hazard Source</th><th>Body Parts At Risk</th><th>Severity</th><th>Probability</th><th>Risk Code</th><th>Control Method*</th></tr><tr><td>Pick up stock</td><td>Cuts</td><td>Sharp metal</td><td>hands</td><td>III</td><td>C</td><td>2</td><td>Leather gloves while handling</td></tr><tr><td></td><td>Sprain</td><td>Heavy metal</td><td>back</td><td>II</td><td>C</td><td>2</td><td>Hoist for heavy items</td></tr><tr><td></td><td>Crush</td><td>Heavy metal</td><td>feet</td><td>II</td><td>C</td><td>N</td><td>Steel Toed Shoes</td></tr><tr><td>Run Lathe</td><td>Impact</td><td>Revolving chuck</td><td>hands</td><td>II</td><td>C</td><td>N</td><td>Chuck guard</td></tr><tr><td></td><td>Impact</td><td>Metal Chips</td><td>face, eyes, hands</td><td>II</td><td>B</td><td>1</td><td>Safety Glasses, face shield, coveralls</td></tr><tr><td></td><td>Chemical</td><td>Coolant/Lube</td><td>hands</td><td>III</td><td>C</td><td>z N</td><td>Switch to non-irritating mixture</td></tr><tr><td></td><td>Repetitive Motion</td><td>Frequent control adjust</td><td>hands</td><td>II</td><td>D</td><td>3</td><td>Periodic rest breaks, vary task duties</td></tr><tr><td>Remove stock</td><td>(Same as</td><td>Pick up</td><td>stock)</td><td></td><td></td><td></td><td></td></tr><tr><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td></tr><tr><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td></tr><tr><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td></tr><tr><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td></tr><tr><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td></tr><tr><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td></tr><tr><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><

[11] Safety Data Sheet - Formic Acid

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# SAFETY DATA SHEET (cont.) ## Protective Equipment and Precautions for Firefighters (cont.) Formic acid Revision Date 25-Nov-2022 <table><tr><th></th><th>6. Accidental release measures</th></tr><tr><td>Personal Precautions</td><td>Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Ensure adequate ventilation. Remove all sources of ignition. Take precautionary measures against static discharges.</td></tr><tr><td>Environmental Precautions</td><td>Should not be released into the environment. Do not flush into surface water or sanitary sewer system. See Section 12 for additional Ecological Information.</td></tr><tr><td colspan="2">Methods for Containment and Clean Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Up Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.</td></tr></table> <table><tr><th colspan="2">7. Handling and storage</th></tr><tr><td>Handling</td><td>Use only under a chemical fume hood. Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Do not breathe mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical assistance. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. Take precautionary measures against static discharges.</td></tr><tr><td>Storage.</td><td>Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks and flame. Containers should be vented periodically in order to overcome pressure buildup. Store in explosion-proof refrigerator. Flammables area. Incompatible Materials. Strong oxidizing agents. Metals. Finely powdered metals. Strong bases.</td></tr></table> ## 8. Exposure controls / personal protection ## Exposure Guidelines <table><tr><th>Component</th><th>ACGIH TLV</th><th>OSHA PEL</th><th>NIOSH</th><th>Mexico OEL (TWA)</th></tr><tr><t

[12] Personal Protective Equipment (PPE) Guide

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# A. Introduction (cont.) ## Hierarchy of Controls (cont.) requirements under WAC [redacted identifier] Personal Protective Equipment (PPE). The next section tells you what you must do if your employees need PPE. Examples of some PPE: <table><tr><th>Body part</th><th>Example of PPE</th><th>Example of hazard/ hazardous condition</th></tr><tr><td>Head</td><td>hard hat</td><td>contact from falling object</td></tr><tr><td>Face</td><td>face shield</td><td>impact from flying wood chips</td></tr><tr><td>Eyes</td><td>safety glasses</td><td>liquid chemical splash</td></tr><tr><td>Body (torso)</td><td>leather apron</td><td>burn from molten metal work</td></tr><tr><td>Arms, hands</td><td>puncture-resistant metal- mesh gloves</td><td>cut from shellfish processing</td></tr><tr><td>Legs, feet</td><td>knee guards</td><td>awkward posture, pressure from carpet laying</td></tr><tr><td rowspan="2">Potentially life-threatening</td><td>life jacket (personal flotation device)</td><td>drowning from falling into water</td></tr><tr><td>*body harness/personal fall protection system</td><td>*fall from roof</td></tr><tr><td>Ears</td><td>*ear plugs</td><td>*loud noise from machinery</td></tr><tr><td>Lungs</td><td>*face mask with cartridge</td><td>*vapors from cleaning with solvent</td></tr></table> * PPE for these and other hazards are not included in this volume of the PPE Guide but will be covered in future volumes (see WAC 296-62 for respiratory and hearing protection and WAC 296-155 for fall protection for further assessment). 7

[13] Personal Protective Equipment (PPE) Hazard Assessment Tool

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# Hazard assessment worksheet: Torso protection (cont.) ## PPE required (cont.) OSHA Oregon OSHA Department of Consumer and Business Services # Hazard assessment worksheet: Eye and face protection Salem Central Office [redacted street address]. NE Salem, OR [redacted postal code] Phone: [redacted phone] Toll-free: [redacted phone] osha.oregon.gov Work task: Date ## Potential hazards - No hazards requiring eye and face protection - Dust, dirt, metal, or wood chips from chipping, grinding, sawing, hammering, and from power tools - Chemical splashes from corrosive substances, hot liquids, and solvents - Objects such as tree limbs, chains, tools, and ropes that swing into the eyes or face - Radiant energy from welding and harmful rays from lasers or other radiant light - Other hazard: ## PPE required - None required - Chemical goggles Face shield - Chemical splash goggles Glasses or goggles with face shield Impact goggles Welding hood Welding helmet Safety glasses with side shields ............... Safety goggles with face shield Welding goggles Other PPE: 440-5871 (07/23/COM)

[14] FACT SHEET: Personal Protective Equipment

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## Why use PPE? (cont.) PERSONAL PROTECTIVE EQUIPMENT # Employer responsibility Survey your workplace Conduct a hazard assessment to determine if employees need PPE. OAR [redacted phone](1) requires a written document that certifies that the workplace has been evaluated, the dates of the hazard assessment, ## Table 1 and who performed the evaluation. Hazard assessments should be re-evaluated whenever there are changes to equipment, processes, or chemicals in the workplace. See an example of a hazard assessment in Table 1, below. Another example is our PPE Hazard Assessment and Certification Form. <table><tr><th colspan="4">PPE Hazard Assessment (example)</th></tr><tr><td colspan="2">Department: Building maintenance</td><td colspan="2">Job title: Maintenance specialist</td></tr><tr><td colspan="4">Job duty location: Plant-wide</td></tr><tr><td colspan="4">Analysis performed by: Jada Robinson Date: Dec. 19, 2023</td></tr><tr><td>Activity/tools</td><td>Potential hazards</td><td>Body parts</td><td>PPE required</td></tr><tr><td>Replace glass</td><td>1,7</td><td>c, g, h</td><td>III, VII (cut resistant)</td></tr><tr><td>Remove trash</td><td>7</td><td>C</td><td>III</td></tr><tr><td>Replace light bulbs</td><td>1, 4, 7</td><td>c, h</td><td>III, VII (cloth/leather)</td></tr><tr><td>Welding</td><td>3,7,8</td><td>c, e, f, g, h</td><td>X (welding helmet/lens) IX (fume) X (welding vest) VII (welding gloves)</td></tr></table> ## Hazard key 1. Cut 2. Abrasion 3. Burn 4. Fall 5. Flying object 6. Noise 7. Flying particles 8. Inhalation 9. Slip 10. Splash 11. Other Body part key a. Head b. Face c. Eye(s) d. Ear(s) e. Respiratory f. Trunk g. Arm(s) h. Hand(s) i. Finger(s) j. Leg(s) k. Foot/feet I. Toe(s) m. Other PPE required key I. Hard hat - II. Chemical goggles - III. Safety glasses - IV. Ear plugs V. Ear muffs - VI. Body harness - VII. Gloves (list type) - VIII. Shoes/boots (list type) - IX. Respirator X. Other OSHA Oregon OSHA Departm

[15] Spill Response - Chemicals

Page 4

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# Spill Response - Chemicals (cont.) ## What should be in a spill response kit? (cont.) - Personal protective equipment appropriate for the chemicals present - Absorbent material or other methods to contain the spills (e.g., sand, absorbent socks, etc.) - Neutralizing material - Shovel, scoops, pans, containers, vacuum, broom, and dustpan, as needed, and made of appropriate material - Heavy-duty trash bags or containers for the waste - Labels for identification of the hazardous waste - Caution tape to isolate the spill area - First aid supplies, where appropriate - Other equipment as needed, such as tongs or forceps to pick up broken glass - Communication devices (e.g., radio, phone) Specialty spill kits may be necessary for chemicals such as mercury, acids, bases, hydrofluoric acid, etc. ## What are some precautions to know when a spill occurs? - Only attempt to clean a spill if you are adequately trained to do so and have the correct equipment - Leave the area immediately if you are not trained to handle the spill or if it is clearly beyond your control - If you are ever in doubt of your ability to clean a chemical spill safely, evacuate the area and call for help - Alert other people in the area to the emergency - If there is a risk to the area, pull the fire alarm (or use a designated alarm signal) and evacuate - Report the problem to those responsible for handling spill response or emergencies - If possible, and if safe to do so, contain the source of the spill or leak and turn off any sources of ignition (open flames, electrical equipment, etc.) - First aid is always the top priority. If you spill a hazardous chemical on yourself, remove any potentially contaminated clothing immediately and use the emergency shower. If the chemical enters your eye, flush for at least 15 minutes at the eyewash station. For some chemicals, you may need to flush for up to 60 minutes - review the SDS beforehand and know the rinsing times. - Only trained peopl

[16] Personal Protective Equipment (PPE) Guide

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# Hand And Arm Protection (cont.) ## Common types of protective gloves (cont.) <table><tr><th>Types</th><th>Protection</th><th>Use/Properties</th></tr><tr><td>Leather gloves</td><td> sparks • moderate heat • blows • chips • scraping against rough objects</td><td>• welding can be also used in combination with an insulated liner when working with electricity</td></tr><tr><td>Aluminized gloves</td><td>• insulation against intense heat</td><td>• most commonly when working with molten materials - welding, furnace, and foundry work • requires an insert made of synthetic materials that protect against heat and cold</td></tr><tr><td>Aramid fiber</td><td> heat and cold • cut- and abrasive-resistant</td><td>synthetic material; wears well</td></tr><tr><td>Metal Mesh</td><td> cuts and scratches</td><td>most commonly when working with cutting tools or other sharp instruments</td></tr><tr><td>Other synthetic materials</td><td>heat and cold • cut- and abrasive-resistant may withstand some diluted acids (but not alkalis and solvents)</td><td></td></tr><tr><td>Fabric and coated fabric gloves</td><td>Varying degrees</td><td>Generally used to improve grip when handling slippery objects. They also help insulate hands from mild heat or cold</td></tr><tr><td>-Fabric</td><td>Dirt, slivers, chafing, and abrasion</td><td>Does not provide sufficient protection against rough, sharp, or heavy materials</td></tr><tr><td>-Coated fabric</td><td>General-purpose slip-resistant hand protection</td><td>Handling bricks, wire rope, chemical containers, etc. Cotton flannel with napping on one side, plastic coating on unnapped side</td></tr><tr><td>Chemical and liquid resistant gloves *</td><td>Burns, irritation, and dermatitis caused by contact with oils, greases, solvents, and other chemicals; also reduces the risk of exposure to blood and other potentially infectious substances</td><td></td></tr><tr><td>-Butyl rubber</td><td>Nitric acid, sulfuric acid, hydrofluoric acid, red fuming nitric acid, ro

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