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For PLANISEAL CR2 H, the most relevant safety documentation in the provided sources is the SDS for Part A, with additional hazard information available for Part B. For Part A, hazard identification shows it is classified as Eye Irritation Category 2A, Skin Sensitization Category 1, and Acute Aquatic Hazard Category 3. Key hazard statements are that it causes serious eye irritation, may cause an allergic skin reaction, and is harmful to aquatic life. Part A also contains low concentrations of free crystalline silica, which is identified as STOT RE 1 and Carc. 1A at the ingredient level, and silica is listed on IARC, OSHA, NIOSH, and NTP carcinogen listings. [3] [3] [6] [8]

Health and safety requirements should be based on the SDS precautionary statements, exposure prevention measures, and task-specific risk assessment.

  • Read and understand all safety precautions before handling.
  • Avoid breathing mist, vapours, or spray.
  • Wash skin thoroughly after handling.
  • Wear protective gloves, protective clothing, and eye/face protection.
  • Avoid release to the environment.
  • Use eyewash and washing facilities near the work area, and remove/wash contaminated clothing before reuse.
  • For Part B or any operation with inadequate ventilation or inhalation potential, use only outdoors or in a well-ventilated area and wear respiratory protection if ventilation is inadequate.

[3] [5] [9] A practical risk assessment for this product should consider the task, exposure route, duration, ventilation, and environmental release potential. The main foreseeable risks for Part A are eye contact, skin sensitization, and environmental contamination. If the full system includes Part B, inhalation and respiratory sensitization risks increase significantly because Part B is classified as harmful if inhaled, may cause allergy or asthma symptoms or breathing difficulties if inhaled, and may cause respiratory irritation. Risk is higher during mixing, spraying, transfer, spill cleanup, or work in enclosed or poorly ventilated spaces. [2] [8] [5]

Recommended control measures and safe operating procedures:

  • Verify the correct product part before use and review the current SDS for each component.
  • Perform work in a well-ventilated area; where mist, vapour, or spray may be generated, use local exhaust or other engineering controls.
  • Prevent eye and skin contact by using safety glasses with side shields, chemical-resistant impervious gloves, suitable protective clothing, and task-appropriate footwear.
  • Keep containers closed when not in use, avoid unnecessary handling, and minimize splash, mist, and spill generation.
  • Do not eat, drink, or smoke while handling; wash thoroughly after use.
  • Prevent spills from reaching drains, soil, waterways, and sewers.
  • Do not reuse empty containers; dispose of product residues and contaminated packaging through approved waste channels.

[9] [9] [7] [8] Incident prevention should focus on preventing exposure and ensuring prompt first aid. For skin contact, remove contaminated clothing and wash immediately with soap and plenty of water; obtain medical attention if symptoms persist. For eye contact, rinse with water for a sufficient length of time and seek immediate ophthalmologic or medical attention. If inhaled, move the person to fresh air and keep them warm and at rest. If swallowed, do not induce vomiting; get medical attention and show the SDS or label. Workers should be trained to recognize allergic skin reactions, persistent eye irritation, and any breathing difficulty as triggers for immediate reporting and medical evaluation. [6] [6] [6] [3]

For regulatory compliance, maintain the current SDS, ensure workplace labeling and hazard communication are consistent with OSHA/WHMIS requirements, and verify site-specific federal, state, provincial, and local obligations. For Part A, all components are listed on TSCA, and the product notes state that user activities must comply with applicable laws. State right-to-know and Proposition 65 implications should be reviewed because free crystalline silica is listed under California Proposition 65 and several state right-to-know programs. Transport information for Part A indicates it is not classified as dangerous for transport under DOT, ADR, IATA, or IMDG. [7] [4] [4] [7]

In summary, the core safety documentation package for work involving Planiseal CR2 H should include: the current SDS for each part used, a task-specific risk assessment, documented PPE and ventilation requirements, spill and waste procedures, first-aid instructions, worker training records, and a regulatory review for silica and local environmental/disposal obligations. If the work involves only Part A, the primary controls are for eye, skin sensitization, and environmental protection. If Part B is also used, respiratory hazard controls become essential and should include ventilation and respiratory protection where needed. [1] [5]

9 source record(s)

Sources used for this answer

[1] H&C Cool Feel

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# Section 8. Exposure controls/personal protection <table><tr><th>Ingredient name</th><th>CAS #</th><th>Exposure limits</th></tr><tr><td>Glass, oxide, chemicals</td><td>[redacted postal code]-17-3</td><td>NOM-010-STPS-2014 (Mexico, 4/2016) [Fibras vítreas sintéticas, fibra de lana mineral] A3. TWA 8 hours: 1 fibers/cm³. NOM-010-STPS-2014 (Mexico, 4/2016) [Fibras vítreas sintéticas, filamento de fibra de vidrio continuo] A4. TWA 8 hours: 5 mg/m3. Form: Inhalable fraction. TWA 8 hours: 1 fibers/cm3. Form: Inhalable fraction.</td></tr></table> Biological exposure indices (United States) No exposure indices known. Biological exposure indices (Canada) No exposure indices known. Biological exposure indices (Mexico) No exposure indices known. ## Appropriate engineering controls Environmental exposure controls : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. ## Individual protection measures Hygiene measures ## Eye/face protection ## Skin protection Hand protection ## Body protection ## Other skin protection : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. : Safety eyewear complying with an approved standard should be used when a risk assessment indic…

[2] MAPEI - Planiseal CR2 H - Part A

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# Safety Data Sheet PLANISEAL CR2 H PART A (cont.) ## 15. REGULATORY INFORMATION (cont.) <table><tr><th>No substances listed</th></tr><tr><td>Section 313 - Toxic chemical list:</td></tr><tr><td>No substances listed</td></tr><tr><td>CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act</td></tr><tr><td>Substance(s) listed under CERCLA:</td></tr><tr><td>No substances listed</td></tr><tr><td>CAA - Clean Air Act</td></tr><tr><td>CAA listed substances:</td></tr><tr><td>No substances listed</td></tr><tr><td>CWA - Clean Water Act</td></tr><tr><td>CWA listed substances:</td></tr><tr><td>No substances listed</td></tr><tr><td>USA - State specific regulations</td></tr><tr><td>California Proposition 65</td></tr><tr><td>Substance(s) listed under California Proposition 65:</td></tr><tr><td>free crystalline silica (0 &gt; 10 µ) Listed as carcinogen</td></tr><tr><td>Massachusetts Right to know</td></tr><tr><td>Substance(s) listed under Massachusetts Right to know:</td></tr><tr><td>free crystalline silica (0 &gt; 10 µ)</td></tr><tr><td>Pennsylvania Right to know</td></tr><tr><td>Substance(s) listed under Pennsylvania Right to know:</td></tr><tr><td>free crystalline silica (Ø &gt; 10 µ)</td></tr><tr><td>New Jersey Right to know</td></tr><tr><td>Substance(s) listed under New Jersey Right to know:</td></tr><tr><td>free crystalline silica (0 &gt; 10 µ)</td></tr><tr><td>Canada - Federal regulations</td></tr><tr><td>DSL - Domestic Substances List</td></tr><tr><td>All the substances are listed in the DSL.</td></tr><tr><td>NDSL - Non Domestic Substances List</td></tr><tr><td>This product complies with NDSL inventory</td></tr><tr><td>NPRI - National Pollutant Release Inventory</td></tr><tr><td>NPRI (National Pollutant Release Inventory) - List of substances listed.</td></tr><tr><td>No substances listed</td></tr></table> ## 16. OTHER INFORMATION Safety Data Sheet dated: 9/24/2024 - version 5 Reasonable care has been taken in the preparation of this information, b…

[3] MAPEI - Planiseal CR2 H - Part A

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# Safety Data Sheet PLANISEAL CR2 H PART A (cont.) ## Waste treatment methods (cont.) Dispose of containers contaminated by the product in accordance with local or national legal provisions. For further information, contact your local waste authority. Special precautions: This material and its container must be disposed of in a safe way. Care should be taken when handling untreated empty containers. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Empty containers or liners may retain some product residues. Do not re-use empty containers. ## 14. TRANSPORT INFORMATION <table><tr><th>Not classified as dangerous in the meaning of transport regulations. UN number</th></tr><tr><td>DOT-UN Number: Not Applicable</td></tr><tr><td>ADR-UN number: Not Applicable</td></tr><tr><td>IATA-Un number: Not Applicable</td></tr><tr><td>IMDG-Un number: Not Applicable</td></tr><tr><td>UN proper shipping name</td></tr><tr><td>DOT-Proper Shipping Name: Not Applicable</td></tr><tr><td>ADR-Shipping Name: Not Applicable</td></tr><tr><td>IATA-Technical name: Not Applicable</td></tr><tr><td>IMDG-Technical name: Not Applicable</td></tr><tr><td>Transport hazard class(es)</td></tr><tr><td>DOT-Hazard Class: Not Applicable</td></tr><tr><td>ADR-Class: Not Applicable</td></tr><tr><td>IATA-Class: Not Applicable</td></tr><tr><td>IMDG-Class: Not Applicable</td></tr><tr><td>Packing group</td></tr><tr><td>DOT Packing Group: Not Applicable</td></tr><tr><td>ADR-Packing Group: Not Applicable</td></tr><tr><td>IATA-Packing group: Not Applicable</td></tr><tr><td>IMDG-Packing group: Not Applicable</td></tr><tr><td>Environmental hazards</td></tr><tr><td>Marine pollutant: No</td></tr><tr><td>Environmental Pollutant: Not Applicable</td></tr><tr><td>DOT-RQ: No</td></tr><tr><td>Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code</td></tr><tr><td>Not Applicable</td></tr><tr><td>Special precautions</td></tr><tr><td>Department of Transportation (…

[4] MAPEI - Planiseal CR2 H - Part A

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# Safety Data Sheet PLANISEAL CR2 H PART A (cont.) ## 9. PHYSICAL AND CHEMICAL PROPERTIES (cont.) <table><tr><th></th><th></th><th>LD50 Skin Rabbit = 10.8 ml/kg LC50 Inhalation Rat &gt; 3.8 mg/l 4h</th></tr><tr><td>free crystalline silica (Ø &gt;10 µ)</td><td>a) acute toxicity</td><td>LD50 Oral &gt; 2000 mg/kg LD50 Skin &gt; 2000 mg/kg</td></tr><tr><td>bis(1,2,2,6,6- pentamethyl-4-piperidyl) sebacate</td><td>a) acute toxicity</td><td>LD50 Oral Rat = 2615 mg/kg</td></tr></table> Substance(s) listed on the IARC Monographs: free crystalline silica (Ø > 10 µ) Group 1 Substance(s) listed as OSHA Carcinogen(s): free crystalline silica (Ø > 10 µ) Substance(s) listed as NIOSH Carcinogen(s): free crystalline silica (Ø > 10 µ) Substance(s) listed on the NTP report on Carcinogens: free crystalline silica (Ø > 10 µ) ## 12. ECOLOGICAL INFORMATION ## Toxicity Adopt good working practices, so that the product is not released into the environment. Eco-Toxicological Information: ## List of Eco-Toxicological properties of the product The product is classified: Acute aquatic hazard, category 3(H402) List of Eco-Toxicological properties of the components Component Ident. Numb. Ecotox Data bis(1,2,2,6,6-pentamethyl-4- CAS: [redacted postal code]-26- a) Aquatic acute toxicity : EC50 Daphnia = 20 mg/L 24h piperidyl) sebacate 7 EINECS: 255-437-1 a) Aquatic acute toxicity : LC50 Fish Lepomis macrochirus = 0.97 mg/L 96h Persistence and degradability N.A. Bioaccumulative potential N.A. Mobility in soil N.A. Other adverse effects N.A. ## 13. DISPOSAL CONSIDERATIONS ## Waste treatment methods The generation of waste should be avoided or minimized wherever possible. Recover if possible. Methods of disposal: Disposal of this product, solutions, packaging and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and nonrecyclable products…

[5] MAPEI - Planiseal CR2 H - Part A

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# Safety Data Sheet PLANISEAL CR2 H PART A MAPEI® Safety Data Sheet dated: 09/24/2024 - version 5 Date of first edition: 09/09/2020 ## 1. IDENTIFICATION Product identifier Mixture identification: Trade name: PLANISEAL CR2 H PART A Trade code: 9024383 Recommended use of the chemical and restrictions on use Recommended use: Adhesive Restrictions on use: Not available Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party Company: MAPEI CORP. (USA and Puerto Rico) [redacted street address] - [redacted postal code] - Deerfield Beach - FL - USA Phone: [redacted phone] Responsable: [redacted email] Emergency 24 hour numbers: Emergency Number (USA/Canada) CHEMTREC 1(800) 424-9300 / 1(703) 527-3887 Emergency Transport CANUTEC (Canada) 1-[redacted phone] ## 2. HAZARD(S) IDENTIFICATION ! Classification of the chemical Eye irritation, Category 2A Skin Sensitization, Category 1 Acute aquatic hazard, category 3 Label elements Hazard pictograms and Signal Word Causes serious eye irritation. May cause an allergic skin reaction. Harmful to aquatic life ! Warning ## Hazard statements <table><tr><th>H317</th><th>May cause an allergic skin reaction.</th></tr><tr><td>H319</td><td>Causes serious eye irritation.</td></tr><tr><td>H402</td><td>Harmful to aquatic life</td></tr></table> ## Precautionary statements <table><tr><th>P201</th><th>Obtain special instructions before use.</th></tr><tr><td>P202</td><td>Do not handle until all safety precautions have been read and understood.</td></tr><tr><td>P261</td><td>Avoid breathing mist/vapours/spray.</td></tr><tr><td>P264</td><td>Wash skin thoroughly after handling.</td></tr><tr><td>P273</td><td>Avoid release to the environment.</td></tr><tr><td>P280</td><td>Wear protective gloves/protective clothing/eye protection/face protection.</td></tr><tr><td>P302+P352</td><td>IF ON SKIN: Wash with plenty of water.</td></tr><tr><td>P305+P351+P33 8</td><td>IF IN EYES: Rinse cautiously with w…

[6] MAPEI - Planiseal CR2 H - Part A

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# Safety Data Sheet PLANISEAL CR2 H PART A (cont.) ## Precautionary statements (cont.) Ingredient(s) with unknown acute toxicity: None Hazards not otherwise classified identified during the classification process: None ## 3. COMPOSITION/INFORMATION ON INGREDIENTS Substances Not Relevant Mixtures Hazardous components within the meaning of 29 CFR 1910.1200 and related classification: List of components <table><tr><th>Qty</th><th>Name</th><th>Ident. Numb.</th><th>Classification</th></tr><tr><td>1-2.5 %</td><td>ethohexadiol; 2-ethylhexane-1,3-diol</td><td>CAS:94-96-2 EC:202-377-9 Index:603-087-00-9</td><td>Eye Dam. 1, H318</td></tr><tr><td>0.1-0.25 %</td><td>free crystalline silica (Ø &gt;10 µ)</td><td>CAS:[redacted postal code]-60-7 EC:238-878-4</td><td>STOT RE 1, H372; Carc. 1A, H350</td></tr><tr><td>0.1-0.25%</td><td>bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate</td><td>CAS:[redacted postal code]-26-7 EC:255-437-1</td><td>Skin Sens. 1, H317; Aquatic Acute 1, H400; Aquatic Chronic 1, H410</td></tr></table> ## 4. FIRST AID MEASURES Description of first aid measures <table><tr><th>In case of skin contact:</th></tr><tr><td>Immediately take off all contaminated clothing. OBTAIN IMMEDIATE MEDICAL ATTENTION.</td></tr><tr><td>Obtain medical attention if skin related symptoms persist.</td></tr><tr><td>Remove contaminated clothing immediately and dispose of safely.</td></tr><tr><td>After contact with skin, wash immediately with soap and plenty of water.</td></tr><tr><td>In case of eyes contact:</td></tr><tr><td>After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist immediately.</td></tr><tr><td>Protect uninjured eye.</td></tr><tr><td>In case of Ingestion:</td></tr><tr><td>Do not induce vomiting, get medical attention showing the SDS and the hazard label.</td></tr><tr><td>In case of Inhalation:</td></tr><tr><td>Remove casualty to fresh air and keep warm and at rest.</td></tr><tr><td>Most im…

[7] MAPEI - Planiseal CR2 H - Part A

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# Safety Data Sheet PLANISEAL CR2 H PART A (cont.) ## 9. PHYSICAL AND CHEMICAL PROPERTIES (cont.) <table><tr><th>Vapour pressure: Not Relevant</th><th></th></tr><tr><td>Relative density: 1.15 g/cm3</td><td></td></tr><tr><td>Solubility in water: Insoluble</td><td></td></tr><tr><td>Solubility in oil: partly soluble</td><td></td></tr><tr><td>Partition coefficient (n-octanol/water):</td><td>Not Relevant</td></tr><tr><td>Auto-ignition temperature: Not</td><td>Relevant</td></tr><tr><td>Decomposition temperature: Not</td><td>Relevant</td></tr><tr><td>Viscosity: Not Relevant</td><td></td></tr><tr><td>Kinematic viscosity: &gt; 20,5 mm2/sec</td><td>(40 °C) mm2/s</td></tr><tr><td>Explosive properties: Not Relevant</td><td></td></tr><tr><td>Oxidizing properties: Not Relevant</td><td></td></tr><tr><td>Solid/gas flammability: Not Relevant</td><td></td></tr><tr><td>Other information</td><td></td></tr><tr><td>Substance Groups relevant properties</td><td>Not Relevant</td></tr><tr><td>Miscibility: Not Relevant</td><td></td></tr><tr><td>Fat Solubility: Not Relevant</td><td></td></tr><tr><td>Conductivity: Not Relevant</td><td></td></tr><tr><td colspan="2">10. STABILITY AND REACTIVITY</td></tr><tr><td>Reactivity</td><td></td></tr><tr><td>Stable under normal conditions</td><td></td></tr><tr><td>Chemical stability</td><td></td></tr><tr><td>Data not available.</td><td></td></tr><tr><td>Possibility of hazardous reactions</td><td></td></tr><tr><td>None.</td><td></td></tr><tr><td>Conditions to avoid</td><td></td></tr><tr><td>Stable under normal conditions.</td><td></td></tr><tr><td>Incompatible materials</td><td></td></tr><tr><td>None in particular.</td><td></td></tr><tr><td>Hazardous decomposition products</td><td></td></tr><tr><td>None.</td><td></td></tr><tr><td colspan="2">11. TOXICOLOGICAL INFORMATION</td></tr><tr><td>Information on toxicological effects</td><td></td></tr><tr><td colspan="2">Toxicological Information of the Preparation</td></tr><tr><td>a) acute toxicity</td><td>Not clas…

[8] MAPEI - Planiseal CR2 H - Part B

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Safety Data Sheet PLANISEAL CR2 H /B Safety Data Sheet dated: 02/18/2022 - version 5 Date of first edition: 04/13/2020 MAPEI® ## 1. IDENTIFICATION Product identifier Mixture identification: Trade name: PLANISEAL CR2 H /B Trade code: 9024384 Recommended use of the chemical and restrictions on use Recommended use: Polyurethane membrane Restrictions on use: Not available Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party Company: MAPEI CORP. (USA and Puerto Rico) [redacted street address] - [redacted postal code] - Deerfield Beach - FL - USA Phone: [redacted phone] Responsable: [redacted email] Emergency 24 hour numbers: Emergency Number (USA/Canada) CHEMTREC 1(800) 424-9300 / 1(703) 527-3887 Emergency Transport CANUTEC (Canada) 1-[redacted phone] ## 2. HAZARD(S) IDENTIFICATION ! Classification of the chemical Skin Irrit. 2 Causes skin irritation. Eye Irrit. 2B Causes eye irritation Skin Sens. 1 May cause an allergic skin reaction. Acute Tox. 4 Harmful if inhaled. Resp. Sens. 1 May cause allergy or asthma symptoms or breathing difficulties if inhaled. STOT SE 3 May cause respiratory irritation. ## Label elements Hazard pictograms and Signal Word ! Danger ## Hazard statements <table><tr><th>H315</th><th>Causes skin irritation.</th></tr><tr><td>H317</td><td>May cause an allergic skin reaction.</td></tr><tr><td>H320</td><td>Causes eye irritation</td></tr><tr><td>H332</td><td>Harmful if inhaled.</td></tr><tr><td>H334</td><td>May cause allergy or asthma symptoms or breathing difficulties if inhaled.</td></tr><tr><td>H335</td><td>May cause respiratory irritation.</td></tr></table> ## Precautionary statements P261 Avoid breathing mist/vapours/spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P280 Wear protective gloves. P285 In case of inadequate ventilation wear respiratory prote…

[9] MAPEI - Planiseal CR2 H - Part A

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# Safety Data Sheet PLANISEAL CR2 H PART A (cont.) ## 16. OTHER INFORMATION (cont.) A.9/1 STOT RE 1 US-HAE/A1 Aquatic Acute 1 US-HAE/C1 Aquatic Chronic 1 Specific target organ toxicity following repeated exposure, Category 1 Acute aquatic hazard, category 1 Chronic (long term) aquatic hazard, category 1 ## Legend to abbreviations and acronyms used in the safety data sheet: ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road. RID: Regulation Concerning the International Transport of Dangerous Goods by Rail. IMDG: International Maritime Code for Dangerous Goods. IATA: International Air Transport Association. IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA). ICAO: International Civil Aviation Organization. ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO). GHS: Globally Harmonized System of Classification and Labeling of Chemicals. CLP: Classification, Labeling, Packaging. EINECS: European Inventory of Existing Commercial Chemical Substances. INCI: International Nomenclature of Cosmetic Ingredients. CAS: Chemical Abstracts Service (division of the American Chemical Society). GefStoffVO: Ordinance on Hazardous Substances, Germany. LC50: Lethal concentration, for 50 percent of test population. LD50: Lethal dose, for 50 percent of test population. DNEL: Derived No Effect Level. PNEC: Predicted No Effect Concentration. TLV: Threshold Limiting Value. TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard). STEL: Short Term Exposure limit. STOT: Specific Target Organ Toxicity. WGK: German Water Hazard Class. KSt: Explosion coefficient. ## Paragraphs modified from the previous revision: 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE - COMPANY/UNDERTAKING - 2. HAZARDS IDENTIFICATION - 3. COMPOSITION/INFORMATION ON INGREDIENTS - 5. FIRE-FIGHTING MEASURES - 7. HANDLING AND STORAGE - 8. EXPOSURE CONTROL…

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