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Is powdered zinc and issue

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Published by SALUS

Handling powdered zinc involves several safety hazards and risks. These include potential health effects from inhalation and exposure, as well as the need for specific personal protective equipment (PPE) and adherence to exposure limits.

Health Effects:

  • Inhalation of zinc oxide can cause respiratory irritation.
  • Skin contact may cause irritation. Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • Eye contact can result in irritation, rinse out with plenty of water and remove contact lenses.
  • Swallowing may cause gastrointestinal distress, make victim drink water (two glasses at most). Consult doctor if feeling unwell.

Exposure Limits:

  • USA ACGIH Threshold Limit Values (TLV):
    • TWA: 2 mg/m3 (respirable fraction)
    • STEL: 10 mg/m3 (respirable fraction)
  • USA NIOSH Recommended Exposure Limits:
    • TWA: 5 mg/m3 (dust and fumes)
    • STEL: 10 mg/m3 (fume)
    • Ceiling: 15 mg/m3 (dust)
  • USA OSHA Table Z-1 Limits for Air Contaminants:
    • TWA: 5 mg/m3 (respirable fraction)
    • TWA: 15 mg/m3 (total dust)
    • TWA: 5 mg/m3 (fume)
  • Mexico NOM-010-STPS-2014:
    • TWA: 2 mg/m3 (respirable fraction)
    • STEL: 10 mg/m3 (respirable fraction)
  • Canada:
    • Various provinces have TWA of 2 mg/m3 (respirable particulate matter) and STEL of 10 mg/m3 (respirable particulate matter).

Necessary Personal Protective Equipment (PPE):

  • Respiratory Protection: If ventilation is not adequate, use respiratory protection equipment. Up to 0\.5 mg/m³: Any air-purifying respirator with an N100, R100, or P100 filter.
  • Eye Protection: Wear chemical safety goggles.
  • Skin Protection: Wear chemical protective clothing e.g. gloves, aprons, boots. Gloves made from Polymer laminate are recommended.

Engineering Controls and Hygiene Measures:

  • Use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne contaminant levels below recommended exposure limits.
  • Emergency eyewash stations and safety showers should be available in the work area.
  • Wash hands, forearms, and face thoroughly after handling chemical products.
  • Remove contaminated clothing and protective equipment before entering eating areas.
  • Eating, drinking, and smoking should be prohibited in areas where the material is handled, stored, and processed. [6]

[6] [6] [6] [1] [1] [1] [1] [1] [1] [1] [1] [3] [4] [5] [5] [7] [7] [7] [8] [4] [9] [3] [2] [2]

9 source record(s)

Sources used for this answer

[1] Sherwin-Williams - Duration Exterior Acrylic Latex

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# Section 8. Exposure controls/personal protection <table><tr><th></th><th></th><th>TWA 8 hours: 0.05 mg/m3. Form: respirable fraction. CA British Columbia Provincial (Canada, 4/2024) [silica, crystalline - alpha quartz and cristobalite] Carc 2A, Carc 1. TWA 8 hours: 0.025 mg/m3. Form: Respirable. CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 0.05 mg/m3. Form: Respirable particulate matter.. CA Quebec Provincial (Canada, 2/2024) TWAEV 8 hours: 0.05 mg/m3. Form: respirable aerosol fraction. CA Alberta Provincial (Canada, 3/2023) A2. OEL 8 hours: 0.025 mg/m3. Form: Respirable particulate.</th></tr></table> ## Occupational exposure limits (Mexico) <table><tr><th>Ingredient name</th><th>CAS #</th><th>Exposure limits</th></tr><tr><td>Zinc Oxide</td><td>1314-13-2</td><td>NOM-010-STPS-2014 (Mexico, 4/2016) TWA 8 hours: 2 mg/m3. Form: Respirable fraction. STEL 15 minutes: 10 mg/m3. Form: Respirable fraction.</td></tr><tr><td>Cristobalite, respirable powder</td><td>[redacted postal code]-46-1</td><td>NOM-010-STPS-2014 (Mexico, 4/2016) A2. TWA 8 hours: 0.025 mg/m3. Form: Respirable fraction.</td></tr></table> Biological exposure indices (United States) No exposure indices known. Biological exposure indices (Canada) No exposure indices known. ## Biological exposure indices (Mexico) No exposure indices known. ## Appropriate engineering controls Environmental exposure controls ## Individual protection measures Hygiene measures : : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable leve…

[2] Sherwin-Williams - Duration Exterior Acrylic Latex

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# Section 7. Handling and storage <table><tr><th>Protective measures</th><th>Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.</th></tr><tr><td>Advice on general occupational hygiene</td><td>Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.</td></tr><tr><td>Conditions for safe storage, including any incompatibilities</td><td>Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.</td></tr></table> ## Section 8. Exposure controls/personal protection ## Control parame…

[3] LATICRETE - 4-XLT Rapid White I

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# 4-XLT Rapid White Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). <table><tr><th>Nunavut</th><th>OEL TWA (mg/m³)</th><th>10 mg/m3 10 mg/m3</th></tr><tr><td>Northwest Territories</td><td>OEL STEL (mg/m³)</td><td>20 mg/m3 20 mg/m3</td></tr><tr><td>Northwest Territories</td><td>OEL TWA (mg/m3)</td><td>10 mg/m3 10 mg/m3</td></tr><tr><td>Ontario</td><td>OEL TWA (mg/m³)</td><td>10 mg/m3 (inhalable)</td></tr><tr><td>Prince Edward Island</td><td>OEL TWA (mg/m3)</td><td>10 mg/m3 (inhalable particulate matter)</td></tr><tr><td>Québec</td><td>VEMP (mg/m3)</td><td>10 mg/m3 (containing no Asbestos and &lt;1% Crystalline silica-total dust) 5 mg/m3 (containing no Asbestos and &lt;1% Crystalline silica-respirable dust)</td></tr><tr><td>Saskatchewan</td><td>OEL STEL (mg/m3)</td><td>20 mg/m3</td></tr><tr><td>Saskatchewan</td><td>OEL TWA (mg/m³)</td><td>10 mg/m3</td></tr><tr><td colspan="3">Calcium sulfate dihydrate ([redacted postal code]-24-5)</td></tr><tr><td>USA ACGIH</td><td>ACGIH TWA (mg/m³)</td><td>10 mg/m3 (inhalable particulate matter)</td></tr><tr><td>USA OSHA</td><td>OSHA PEL (TWA) (mg/m3)</td><td>15 mg/m3 (total dust) 5 mg/m3 (respirable fraction)</td></tr><tr><td>USA NIOSH</td><td>NIOSH REL (TWA) (mg/m3)</td><td>10 mg/m3 (total dust) 5 mg/m3 (respirable dust)</td></tr><tr><td>Alberta</td><td>OEL TWA (mg/m3)</td><td>10 mg/m3</td></tr><tr><td>British Columbia</td><td>OEL STEL (mg/m³)</td><td>20 mg/m3 (total dust)</td></tr><tr><td>British Columbia</td><td>OEL TWA (mg/m³)</td><td>10 mg/m3 (total dust) 3 mg/m3 (respirable fraction)</td></tr><tr><td>Manitoba</td><td>OEL TWA (mg/m³)</td><td>10 mg/m3 (inhalable particulate matter)</td></tr><tr><td>Newfoundland &amp; Labrador</td><td>OEL TWA (mg/m3)</td><td>10 mg/m3 (inhalable particulate matter)</td></tr><tr><td>Nova Scotia</td><td>OEL TWA (mg/m³)</td><td>10 mg/m3 (inhalable particulate ma…

[4] Lead

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# Lead (cont.) ## What is the American Conference of Governmental Industrial Hygienists (ACGIH®) recommended exposure limit for lead? (cont.) Engineering Controls: Use a local exhaust ventilation and enclosure, if necessary, to control amount in the air. Use stringent control measures such as process enclosure to prevent product release into the workplace. ## What Personal Protective Equipment (PPE) is needed when working with lead? Eye/Face Protection: Wear chemical safety goggles. Skin Protection: Wear chemical protective clothing e.g. gloves, aprons, boots. ## Respiratory Protection: Up to 0.5 mg/m³: (APF = 10) Any air-purifying respirator with an N100, R100, or P100 filter (including N100, R100, and P100 filtering facepieces) except quarter-mask respirators; or Any supplied-air respirator. Up to 1.25 mg/m3:(APF = 25) Any supplied-air respirator operated in a continuous-flow mode; Any powered, air-purifying respirator with a high-efficiency particulate filter. Up to 2.5 mg/m3 (APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters; Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode; Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter; Any self- contained breathing apparatus with a full facepiece; Any supplied-air respirator with a full facepiece. Up to 50 mg/m3: (APF = 1000) Any supplied-air respirator operated in a pressure-demand or other positive- pressure mode Up to 100 mg/m3: APF = 2000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode APF = Assigned Protection Factor Recommendations apply only to National Institute for Occupational Safety and Health (NIOSH) approved respirators. Refer to the NIOSH Pocket Guide to Chemical Hazards for more information. General Hyg…

[5] Safety Data Sheet - Zinc Oxide

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# SAFETY DATA SHEET (cont.) ## SECTION 2: Hazards identification (cont.) Precautionary statement(s) P273 P391 P501 Avoid release to the environment. Collect spillage. Dispose of contents/ container to an approved waste disposal plant. 2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none ## SECTION 3: Composition/information on ingredients ## 3.1 Substances Formula : OZn Molecular weight : 81.39 g/mol CAS-No. : 1314-13-2 EC-No. : 215-222-5 Index-No. : 030-013-00-7 <table><tr><th>Component</th><th>Classification</th><th>Concentration</th></tr><tr><td colspan="3">Zinc oxide</td></tr><tr><td></td><td>Aquatic Acute 1; Aquatic Chronic 1; H400, H410 M-Factor - Aquatic Acute: 1 M-Factor - Aquatic Chronic: 1</td><td>&lt; = 100 %</td></tr></table> For the full text of the H-Statements mentioned in this Section, see Section 16. ## SECTION 4: First aid measures - 4.1 Description of first-aid measures - If inhaled After inhalation: fresh air. - In case of skin contact - In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. - In case of eye contact - After eye contact: rinse out with plenty of water. Remove contact lenses. - If swallowed - After swallowing: make victim drink water (two glasses at most). Consult doctor if feeling unwell. - 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 - 4.3 Indication of any immediate medical attention and special treatment needed No data available Aldrich 255750 Page 2 of 10 The life science business of Merck KGaA, Darmstadt, Germany operates as MilliporeSigma in the US and Canada lillipoRe SiGMa

[6] LATICRETE - STONETECH Heavy Duty Grout Sealer

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# STONETECH® Heavy Duty Grout Sealer Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), OSHA (PEL), or Canadian provincial governments. <table><tr><th>Zinc oxide (ZnO) (1314-13-2)</th><th colspan="2"></th></tr><tr><td>USA ACGIH</td><td>ACGIH OEL TWA</td><td>2 mg/m3 (respirable particulate matter)</td></tr><tr><td>USA ACGIH</td><td>ACGIH OEL STEL</td><td>10 mg/m3 (respirable particulate matter)</td></tr><tr><td>USA OSHA</td><td>OSHA PEL (TWA) [1]</td><td>5 mg/m3 (fume) 15 mg/m3 (total dust) 5 mg/m3 (respirable fraction)</td></tr><tr><td>USA NIOSH</td><td>NIOSH REL (TWA)</td><td>5 mg/m3 (dust and fume)</td></tr><tr><td>USA NIOSH</td><td>NIOSH REL (STEL)</td><td>10 mg/m3 (fume)</td></tr><tr><td>USA NIOSH</td><td>NIOSH REL (Ceiling)</td><td>15 mg/m3 (dust)</td></tr><tr><td>USA IDLH</td><td>IDLH</td><td>500 mg/m3</td></tr><tr><td>Alberta</td><td>OEL STEL</td><td>10 mg/m3 (respirable)</td></tr><tr><td>Alberta</td><td>OEL TWA</td><td>2 mg/m3 (respirable)</td></tr><tr><td>British Columbia</td><td>OEL STEL</td><td>10 mg/m3 (respirable)</td></tr><tr><td>British Columbia</td><td>OEL TWA</td><td>2 mg/m3 (respirable)</td></tr><tr><td>Manitoba</td><td>OEL STEL</td><td>10 mg/m3 (respirable particulate matter)</td></tr><tr><td>Manitoba</td><td>OEL TWA</td><td>2 mg/m3 (respirable particulate matter)</td></tr><tr><td>New Brunswick</td><td>OEL STEL</td><td>10 mg/m3 (fume)</td></tr><tr><td>New Brunswick</td><td>OEL TWA</td><td>10 mg/m3 (particulate matter containing no Asbestos and &lt;1% Crystalline silica, dust) 5 mg/m3 (fume)</td></tr><tr><td>Newfoundland &amp; Labrador</td><td>OEL STEL</td><td>10 mg/m3 (respirable parti…

[7] Sherwin-Williams - Emerald Exterior Acrylic Latex Paint

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# Section 8. Exposure controls/personal protection Occupational exposure limits (Canada) <table><tr><th>Ingredient name</th><th></th><th>CAS #</th><th>Exposure limits</th></tr><tr><td>Zinc Oxide</td><td></td><td>1314-13-2</td><td>CA Saskatchewan Provincial (Canada, 4/2021) STEL 15 minutes: 10 mg/m3. Form: respirable dust and fume. TWA 8 hours: 2 mg/m3. Form: respirable dust and fume. CA British Columbia Provincial (Canada, 4/2024) TWA 8 hours: 2 mg/m3. Form: Respirable. STEL 15 minutes: 10 mg/m3. Form: Respirable. CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 2 mg/m3. Form: Respirable particulate matter.. STEL 15 minutes: 10 mg/m3. Form: Respirable particulate matter.. CA Quebec Provincial (Canada, 2/2024) TWAEV 8 hours: 2 mg/m3. Form: respirable aerosol fraction. STEV 15 minutes: 10 mg/m3. Form: respirable aerosol fraction. CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 2 mg/m3. Form: Respirable. OEL 15 minutes: 10 mg/m3. Form: Respirable.</td></tr><tr><td colspan="4">Occupational exposure limits (Mexico)</td></tr><tr><td>Ingredient name</td><td></td><td>CAS #</td><td>Exposure limits</td></tr><tr><td>Zinc Oxide</td><td></td><td>1314-13-2</td><td>NOM-010-STPS-2014 (Mexico, 4/2016) TWA 8 hours: 2 mg/m3. Form: Respirable fraction. STEL 15 minutes: 10 mg/m3. Form: Respirable fraction.</td></tr></table> Biological exposure indices (United States) No exposure indices known. Biological exposure indices (Canada) No exposure indices known. Biological exposure indices (Mexico) No exposure indices known. Appropriate engineering controls Environmental exposure controls : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. I…

[8] 3M™ Rubber & Vinyl 80 Spray Adhesive

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# 3M(TM) Rubber & Vinyl 80 Spray Adhesive 09/16/21 for the component. <table><tr><th>Ingredient</th><th>C.A.S. No.</th><th>Agency</th><th>Limit type</th><th>Additional Comments</th></tr><tr><td>MIBK</td><td>108-10-1</td><td>ACGIH</td><td>TWA:20 :STEL:75 ppm</td><td>A3: Confirmed animal carcin.</td></tr><tr><td>MIBK</td><td>108-10-1</td><td>OSHA</td><td>TWA:410 mg/m3(100 ppm)</td><td></td></tr><tr><td>Toluene</td><td>108-88-3</td><td>ACGIH</td><td>TWA:20 ppm</td><td>A4: Not class. as human carcin, Ototoxicant</td></tr><tr><td>Toluene</td><td>108-88-3</td><td>OSHA</td><td>TWA:200 ppm;CEIL:300 ppm</td><td></td></tr><tr><td>Cyclohexane</td><td>110-82-7</td><td>ACGIH</td><td>TWA:100 ppm</td><td></td></tr><tr><td>Cyclohexane</td><td>110-82-7</td><td>OSHA</td><td>TWA:1050 mg/m3(300 ppm)</td><td></td></tr><tr><td>Dimethyl Ether</td><td>115-10-6</td><td>AIHA</td><td>TWA:1880 mg/m3(1000 ppm)</td><td></td></tr><tr><td>Zinc Oxide</td><td>1314-13-2</td><td>ACGIH</td><td>TWA(respirable fraction):2 mg/m3;STEL(respirable fraction):10 mg/m3</td><td></td></tr><tr><td>Zinc Oxide</td><td>1314-13-2</td><td>OSHA</td><td>TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3;TWA(as fume):5 mg/m3</td><td></td></tr><tr><td>Acetone</td><td>67-64-1</td><td>ACGIH</td><td>TWA:250 ppm;STEL:500 ppm</td><td>A4: Not class. as human carcin</td></tr><tr><td>Acetone</td><td>67-64-1</td><td>OSHA</td><td>TWA:2400 mg/m3(1000 ppm)</td><td></td></tr><tr><td>Methyl Acetate</td><td>79-20-9</td><td>ACGIH</td><td>TWA:200 ppm;STEL:250 ppm</td><td></td></tr><tr><td>Methyl Acetate</td><td>79-20-9</td><td>OSHA</td><td>TWA:610 mg/m3(200 ppm)</td><td></td></tr><tr><td>Rosin</td><td>8050-09-7</td><td>ACGIH</td><td>TWA(as Resin, inhalable fraction):0.001 mg/m3</td><td>Dermal/Respiratory Sensitizer</td></tr></table> ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Departmen…

[9] Safety Data Sheet - Zinc Oxide

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# SECTION 8: Exposure controls/personal protection ## 8.1 Control parameters Ingredients with workplace control parameters <table><tr><th>Component</th><th>CAS-No.</th><th>Value</th><th>Control parameters</th><th>Basis</th></tr><tr><td>Zinc oxide</td><td>1314-13-2</td><td>TWA</td><td>2 mg/m3</td><td>USA. ACGIH Threshold Limit Values (TLV)</td></tr><tr><td></td><td></td><td>STEL</td><td>10 mg/m3</td><td>USA. ACGIH Threshold Limit Values (TLV)</td></tr><tr><td></td><td></td><td>TWA</td><td>5 mg/m3</td><td>USA. NIOSH Recommended Exposure Limits</td></tr><tr><td></td><td></td><td>TWA</td><td>5 mg/m3</td><td>USA. NIOSH Recommended Exposure Limits</td></tr><tr><td></td><td></td><td>ST</td><td>10 mg/m3</td><td>USA. NIOSH Recommended Exposure Limits</td></tr><tr><td></td><td></td><td>C</td><td>15 mg/m3</td><td>USA. NIOSH Recommended Exposure Limits</td></tr><tr><td></td><td></td><td>TWA</td><td>5 mg/m3</td><td>USA. Occupational Exposure Limits (OSHA) Table Z-1 Limits for Air Contaminants</td></tr><tr><td></td><td></td><td>TWA</td><td>15 mg/m3</td><td>USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants</td></tr><tr><td></td><td></td><td>TWA</td><td>5 mg/m3</td><td>USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants</td></tr><tr><td></td><td></td><td>PEL</td><td>5 mg/m3</td><td>California permissible exposure limits for chemical contaminants (Title 8, Article 107)</td></tr><tr><td></td><td></td><td>STEL</td><td>10 mg/m3</td><td>California permissible exposure limits for chemical contaminants (Title 8, Article 107)</td></tr><tr><td></td><td></td><td>TWA</td><td>10 mg/m3</td><td>USA. OSHA TABLE Z-1 Limits for Air Contaminants 1910.1000</td></tr><tr><td></td><td></td><td>TWA</td><td>5 mg/m3</td><td>USA. OSHA TABLE Z-1 Limits for Air Contaminants 1910.1000</td></tr><tr><td></td><td></td><td>TWA</td><td>5 mg/m3</td><td>USA. OSHA TABLE Z-1 Limits for Air Contaminants 1910.1000</td></tr><tr><td></td><td></td><td>STEL</td><…

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