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Winery Equipment Operation and Chemical Handling ================================================

Document Number: \[SWP-NUMBER]

Revision Date: \[DATE]

Next Review Date: \[NEXT REVIEW DATE]

Department: \[DEPARTMENT NAME]

1\. Scope


This Safe Work Procedure (SWP) outlines the safety procedures and risk assessments for operating equipment and handling chemicals in a winery environment. It includes requirements for personal protective equipment (PPE) and emergency response protocols.

2\. Definitions


Chemical A substance produced by or used in a reaction involving changes to atoms or molecules. Equipment Machinery or tools used to perform specific tasks in the winemaking process. Personal Protective Equipment (PPE) Clothing and equipment worn to protect the worker from hazards.

3\. Responsibilities


3\.2 Workers

  • Use good industrial hygiene practices and wear recommended personal protection. Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. [2]

4\. Potential Hazards and Risks


HazardRiskControl Measures
Chemical Exposure [1]Skin irritation, eye damage, respiratory issuesUse in well-ventilated areas. Wear impervious gloves and eye protection. Do not mix with other chemical products, except as indicated by the manufacturers. Do not get in eyes. Do not get on skin or clothing. Do not breathe vapors/mists/fumes. Do not take internally.
Airborne Contaminants [3]Respiratory irritation, long-term health effectsUse process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Flammable Materials [8] [9]Fire, explosionKeep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges.
Skin Contact with Chemicals [10] [11]Irritation, dermatitis, allergic reactionsWear appropriate protective gloves and clothing to prevent skin exposure.
Eye Contact with Chemicals [3]Eye irritation, burns, vision impairmentSafety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts.
Improper Chemical Storage [8]Spills, leaks, contaminationKeep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks and flame.
Exposure to Hazardous Vapors [10]Respiratory issues, poisoningUse only under a chemical fume hood. Use explosion-proof electrical/ventilating/lighting equipment.

5\. Personal Protective Equipment (PPE)


The appropriate PPE must be worn at all times when operating equipment or handling chemicals.

  • Impervious Gloves: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. [3]
  • Safety Glasses with Side Shields: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. [3]
  • NIOSH Approved Respirator: A NIOSH approved respirator or filtering face piece, such as N95, is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. [4]
  • Protective Clothing: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. [3]

6\. Equipment and Tools


All equipment must be inspected before use to ensure it is in good working condition.

  • Non-Sparking Tools: Use spark-proof tools and explosion-proof equipment. [6]

[8]

  • Ventilation System: Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. [4]

8\. Safe Work Procedure Steps


  1. Equipment Inspection: Inspect all equipment for damage or wear before use. Ensure all safety guards are in place and functioning correctly.
  2. Ventilation: Ensure adequate ventilation in the work area. Use local exhaust ventilation or other engineering controls to minimize exposure to airborne contaminants.
  3. Don PPE: Wear appropriate PPE, including safety glasses, gloves, and protective clothing. Ensure PPE is in good condition and fits properly.
  4. Follow Procedures: Follow the manufacturer's instructions for operating equipment and handling chemicals. Do not deviate from approved procedures.
  5. Use Correct Tools: Use appropriate tools and equipment for the task. Do not use damaged or defective tools.
  6. Clean Up Spills: Clean up any spills or leaks immediately. Dispose of waste materials properly.
  7. Store Chemicals Properly: Store chemicals in tightly closed containers in a cool, dry, and well-ventilated area.
  8. Wash Hands: Wash hands thoroughly after handling chemicals and before eating, drinking, or smoking.

9\. Precautions and Safety Measures


  • Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. - Ensure that eyewash stations and safety showers are close to the workstation location. [3]
  • Keep out of the reach of children. Store locked up. Keep container tightly closed. Store at room temperature and keep containers closed when not in use. - Regularly inspect storage areas for any signs of leaks or spills. [2]

[4]

  • Avoid discharge into drains, water courses or onto the ground. - Ensure proper disposal of chemical waste in accordance with local, regional, national, territorial, provincial, and international regulations. [7]

10\. Emergency Procedures


10\.1 General Emergency Response

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. [5]

10\.2 Specific Emergency Scenarios

  • Eye contact: Rinse with water. Get medical attention if irritation develops and persists. [7]
  • Ingestion: Rinse mouth. Get medical attention if symptoms occur. [7]

10\.3 Emergency Contact Information

Contact medical personnel immediately in case of significant chemical exposure or physical injury.

Approved by: \[NAME AND POSITION]

Date: \[APPROVAL DATE]

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11 source record(s)

Sources used for this answer

[1] CUSTOM - Vinyl PSA Pressure Sensitive Adhesive

Page 4

Open source document

Source excerpt

# SAFETY DATA SHEET (cont.) ## 5.2 EXTINGUISHING MEDIA (cont.) COMPUTER RODUCT WILLDING CUSTOM 8 ADHESIVE SYSTEMS Conforms to OSHA HazCom 2012 Standard and WHMIS 2015 # SAFETY DATA SHEET - 5.3a. Products of Combustion: May include, and are not limited to: oxides of carbon - 5.3b. Explosion Data i. Sensitivity to Mechanical Impact: Not Available ii. Sensitivity to Static Discharge: Not Available - 5.4 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS Keep upwind of fire. Wear full fire fighting turn-out gear(full bunker gear) and respiratory protection (SCBA). ## Section 6: ACCIDENTAL RELEASE MEASURES - 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. - 6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP - Methods for Containment: Recover all usable material. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). - Methods for Cleaning-Up: Vinyl PSA ## Section 7: HANDLING AND STORAGE ## 7.1 PRECAUTIONS FOR SAFE HANDLING - Handling: - Dispose of unwanted material properly in accordance with all local, regional, national and international regulations. Use in well-ventilated areas. Wear impervious gloves and eye protection. Do not mix with other chemical products, except as indicated by the manufacturers. Do not get in eyes. Do not get on skin or clothing. Do not breathe vapors/mists/fumes. Do not take internally. - General Hygiene Advice: Use good industrial hygiene practices and wear recommended personal protection. Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. ## 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES - Storage: Keep out of the reach of children. Store locked up. Keep container tightly closed. Store at room temperature and keep containers clos

[2] Safety Data Sheet - Furfuryl Alcohol

Page 4

Open source document

Source excerpt

# Furfuryl alcohol Revision Date 28-Mar-2024 ## NFPA Health 4 Flammability 2 Instability 1 Physical hazards N/A <table><tr><th></th><th>6. Accidental release measures</th></tr><tr><td>Personal Precautions</td><td>Ensure adequate ventilation. Use personal protective equipment as required. Keep people away from and upwind of spill/leak. Remove all sources of ignition. Evacuate personnel to safe areas. Take precautionary measures against static discharges.</td></tr><tr><td>Environmental Precautions</td><td>Should not be released into the environment. Do not flush into surface water or sanitary sewer system.</td></tr><tr><td colspan="2">Methods for Containment and Clean Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Up Remove all sources of ignition.</td></tr></table> <table><tr><th></th><th>7. Handling and storage</th></tr><tr><td>Handling</td><td>Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Do not breathe mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical assistance. Keep away from open flames, hot surfaces and sources of ignition.</td></tr><tr><td>Storage.</td><td>Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks and flame. Keep under nitrogen. Incompatible Materials. Strong oxidizing agents.</td></tr></table> ## Exposure Guidelines ## 8. Exposure controls I personal protection <table><tr><th>Component</th><th>ACGIH TLV</th><th>OSHA PEL</th><th>NIOSH</th><th>Mexico OEL (TWA)</th></tr><tr><td>Furfuryl alcohol</td><td>TWA: 0.2 ppm Skin</td><td>(Vacated) TWA: 10 ppm (Vacated) TWA: 40 mg/m3 (Vacated) STEL: 15 ppm (Vacated) STEL: 60 mg/m3 Skin TWA: 50 ppm TWA: 200 mg/m3</td><td>IDLH: 75 ppm TWA: 10 ppm TWA: 40 mg/m3 STEL: 15 ppm STEL: 60 mg/m3</td><td>TWA: 10 ppm STEL: 15 ppm</td></tr></table> ## Legend ACGIH - American Conference of Governmental Industria

[3] Safety Data Sheet - 4-Methyl-2-pentanol (Methyl Isobutyl Carbinol)

Page 3

Open source document

Source excerpt

# SAFETY DATA SHEET (cont.) ## 4. First-aid measures (cont.) (+/-)-4-Methyl-2-pentanol Revision Date 28-Mar-2024 Ingestion Clean mouth with water and drink afterwards plenty of water. Most important symptoms and Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting effects Notes to Physician Treat symptomatically ## 5. Fire-fighting measures Suitable Extinguishing Media Water spray. Carbon dioxide (CO2). Dry chemical. Chemical foam. Water mist may be used to cool closed containers. Unsuitable Extinguishing Media No information available Flash Point 41 °C / 105.8 °F Method - No information available Autoignition Temperature 305 °C / 581 °F Explosion Limits Upper 5.5% Lower 1% Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge No information available Specific Hazards Arising from the Chemical Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Hazardous Combustion Products Carbon monoxide (CO). Carbon dioxide (CO2). Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. ## NFPA <table><tr><th>Health 2</th><th>Flammability 2</th><th>Instability 0</th><th>Physical hazards N/A</th></tr><tr><td colspan="4">6. Accidental release measures</td></tr><tr><td>Personal Precautions Environmental Precautions</td><td colspan="3">Ensure adequate ventilation. Use personal protective equipment as required. Remove all sources of ignition. Take precautionary measures against static discharges. Should not be released into the environment. Do not flush into surface water or sanitary sewer system.</td></tr><tr><td colspan="4">Methods for Containment and Clean Keep in suitable, closed containers for disposal. Soak up with inert absorbent material. Up Remove all sources of ign

[4] Sherwin-Williams - WoodScapes Exterior Acrylic Solid Color House Stain

Page 8

Open source document

Source excerpt

# Section 8. Exposure controls/personal protection Biological exposure indices (United States) No exposure indices known. Biological exposure indices (Canada) No exposure indices known. Biological exposure indices (Mexico) <table><tr><th colspan="2">No exposure indices known.</th></tr><tr><td>Appropriate engineering : controls</td><td>If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.</td></tr><tr><td>Environmental exposure : controls</td><td>Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.</td></tr><tr><td>Individual protection measures</td><td></td></tr><tr><td>Hygiene measures :</td><td>Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.</td></tr><tr><td>Eye/face protection :</td><td>Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields.</td></tr><tr><td>Skin protection</td><td></td></tr><tr><td>Hand protection :</td><td>Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when hand

[5] Safety Data Sheet - Diacetone Alcohol

Page 3

Open source document

Source excerpt

# Diacetone alcohol Revision Date 24-Dec-2021 <table><tr><th>Inhalation</th><th>Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.</th></tr><tr><td>Ingestion</td><td>Clean mouth with water and drink afterwards plenty of water.</td></tr><tr><td>Most important symptoms and effects</td><td>None reasonably foreseeable. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting</td></tr><tr><td>Notes to Physician</td><td>Treat symptomatically</td></tr><tr><td colspan="2">5. Fire-fighting measures</td></tr><tr><td>Suitable Extinguishing Media</td><td>Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.</td></tr><tr><td>Unsuitable Extinguishing Media</td><td>No information available</td></tr><tr><td>Flash Point</td><td>58 °C / 136.4 °F</td></tr><tr><td>Method -</td><td>No information available</td></tr><tr><td>Autoignition Temperature</td><td>643 °C / 1189.4 °F</td></tr><tr><td>Explosion Limits</td><td></td></tr><tr><td>Upper</td><td>6.9 vol %</td></tr><tr><td>Lower</td><td>1.8 vol %</td></tr><tr><td>Sensitivity to Mechanical Impact Sensitivity to Static Discharge</td><td>No information available No information available</td></tr><tr><td colspan="2">Specific Hazards Arising from the Chemical Containers may explode when heated. Flammable. Vapors may form explosive mixtures with air. Vapors may travel to source of</td></tr></table> Specific Hazards Arising from the Chemical ignition and flash back. Hazardous Combustion Products Carbon monoxide (CO). Carbon dioxide (CO2). Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. ## NFPA <table><tr><th>Health</th><th>Flammability Instability Physical hazards</th></tr><tr><td>2</td><td>2 0 N/A</td></tr><tr><td></td><td>6. Accidental release m

[6] BEHR Water-Based Wood Stain White Wash Pickling

Page 2

Open source document

Source excerpt

# SAFETY DATA SHEET (cont.) ## 4. First-aid measures (cont.) <table><tr><th>Eye contact</th><th>Rinse with water. Get medical attention if irritation develops and persists.</th></tr><tr><td>Ingestion</td><td>Rinse mouth. Get medical attention if symptoms occur.</td></tr><tr><td>Most important symptoms/effects, acute and delayed</td><td>Edema. Prolonged exposure may cause chronic effects.</td></tr><tr><td>Indication of immediate medical attention and special treatment needed</td><td>Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.</td></tr><tr><td>General information</td><td>Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.</td></tr><tr><td colspan="2">5. Fire-fighting measures</td></tr><tr><td>Suitable extinguishing media</td><td>Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).</td></tr><tr><td>Unsuitable extinguishing media</td><td>Do not use water jet as an extinguisher, as this will spread the fire.</td></tr><tr><td>Specific hazards arising from the chemical</td><td>During fire, gases hazardous to health may be formed.</td></tr><tr><td>Special protective equipment and precautions for firefighters</td><td>Self-contained breathing apparatus and full protective clothing must be worn in case of fire.</td></tr><tr><td>Fire fighting equipment/instructions</td><td>Move containers from fire area if you can do so without risk.</td></tr><tr><td>Specific methods</td><td>Use standard firefighting procedures and consider the hazards of other involved materials.</td></tr><tr><td>General fire hazards</td><td>No unusual fire or explosion hazards noted.</td></tr><tr><td colspan="2">6. Accidental release measures</td></tr><tr><td>Personal precautions, protective equipment and emergency procedures</td><td>Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing dur

[7] Safety Data Sheet - Glycerin

Page 3

Open source document

Source excerpt

# GLYCERIN (cont.) ## 6. Accidental release measures (cont.) GLYCERIN Revision Date 13-Oct-2023 <table><tr><th></th><th>7. Handling and storage</th></tr><tr><td>Handling</td><td>Wear personal protective equipment/face protection. Ensure adequate ventilation. Avoid contact with skin, eyes or clothing. Avoid ingestion and inhalation.</td></tr><tr><td>Storage.</td><td>Keep containers tightly closed in a dry, cool and well-ventilated place. To maintain product quality, do not store in heat or direct sunlight. Protect from moisture. Do not freeze. Incompatible Materials. Strong oxidizing agents.</td></tr></table> ## 8. Exposure controls I personal protection ## Exposure Guidelines <table><tr><th>Component</th><th>ACGIH TLV</th><th>OSHA PEL</th><th>NIOSH</th><th>Mexico OEL (TWA)</th></tr><tr><td>Glycerin</td><td></td><td>(Vacated) TWA: 10 mg/m3 (Vacated) TWA: 5 mg/m3 TWA: 15 mg/m3 TWA: 5 mg/m3</td><td></td><td>TWA: 10 mg/m3</td></tr></table> ## Legend ACGIH- American Conference of Governmental Industrial Hygienists OSHA Occupational Safety and Health Administration <table><tr><th>Engineering Measures</th><th>Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location.</th></tr><tr><td>Personal Protective Equipment</td><td></td></tr><tr><td>Eye/face Protection</td><td>Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.</td></tr><tr><td>Skin and body protection</td><td>Wear appropriate protective gloves and clothing to prevent skin exposure.</td></tr><tr><td>Respiratory Protection</td><td>Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.</td></tr><tr><td>Recommended Filter t

[8] Safety Data Sheet - Isobutyl Alcohol

Page 4

Open source document

Source excerpt

# Pictogram (cont.) ## 5.1 Extinguishing media (cont.) - 5.2 Special hazards arising from the substance or mixture - Carbon oxides - Combustible. - Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire. - 5.3 Advice for firefighters - Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. - 5.4 Further information - Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system. ## SECTION 6: Accidental release measures - 6.1 Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. - 6.2 Environmental precautions - Do not let product enter drains. Risk of explosion. - 6.3 Methods and materials for containment and cleaning up Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area. - 6.4 Reference to other sections - For disposal see section 13. ## SECTION 7: Handling and storage - 7.1 Precautions for safe handling - Advice on safe handling Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. Advice on protection against fire and explosion Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge. Hygiene measures Immediately change contaminated clothing. Apply preventive

[9] CUSTOM - Wood HP4 4-In-1 Hybrid Polymer Adhesive

Page 4

Open source document

Source excerpt

# SAFETY DATA SHEET (cont.) ## 5.1 FLAMMABILITY (cont.) WILLDING CUSTOM 8 RODUCT ADHESIVE SYSTEMS Conforms to OSHA HazCom 2012 Standard and WHMIS 2015 # SAFETY DATA SHEET - 5.2a. Suitable Extinguishing Media: Carbon dioxide, dry chemicals or alcohol-resistant foam - 5.2b. Unsuitable Extinguishing Media: Water, halones. - 5.3 SPECIFIC HAZARDS ARISING FROM THE CHEMICAL - 5.3a. Products of Combustion: Hazardous combustion products: carbon monoxide, carbon dioxide, silicon dioxide, formaldehyde. - 5.3b. Explosion Data i. Sensitivity to Mechanical Impact: Not Available ii. Sensitivity to Static Discharge: Not Available - 5.4 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS Keep upwind of fire. Wear full fire fighting turn-out gear(full bunker gear) and respiratory protection (SCBA). ## Section 6: ACCIDENTAL RELEASE MEASURES - 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. - 6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP - Methods for Containment: Recover all usable material. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). - Methods for Cleaning-Up: - Dispose of unwanted material properly in accordance with all local, regional, national and international regulations. ## Section 7: HANDLING AND STORAGE ## 7.1 PRECAUTIONS FOR SAFE HANDLING Handling: Use in well-ventilated areas. Wear impervious gloves and eye protection. Do not mix with other chemical products, except as indicated by the manufacturers. Do not get in eyes. Do not get on skin or clothing. Do not breathe vapors/mists/fumes. Do not take internally. Wood HP4 Page 4 of 11

[10] H&C Cool Feel

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Source excerpt

# Section 4. First aid measures Skin contact Ingestion : No known significant effects or critical hazards. : No known significant effects or critical hazards. ## Over-exposure signs/symptoms Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data. ## Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments Protection of first-aiders : No specific treatment. : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. See toxicological information (Section 11) ## Section 5. Fire-fighting measures <table><tr><th>Extinguishing media</th><th></th></tr><tr><td>Suitable extinguishing media</td><td>: Use an extinguishing agent suitable for the surrounding fire.</td></tr><tr><td>Unsuitable extinguishing media</td><td>: None known.</td></tr><tr><td>Specific hazards arising from the chemical</td><td>: In a fire or if heated, a pressure increase will occur and the container may burst.</td></tr><tr><td>Hazardous thermal decomposition products</td><td>: Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides</td></tr><tr><td>Special protective actions for fire-fighters</td><td>: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.</td></tr><tr><td>Special protective equipment for fire-fighters</td><td>

[11] CUSTOM - Wood HP4 4-In-1 Hybrid Polymer Adhesive

Page 5

Open source document

Source excerpt

# SAFETY DATA SHEET (cont.) ## 7.1 PRECAUTIONS FOR SAFE HANDLING (cont.) WILLDING CUSTOM 8 RODUCTS ADHESIVE SYSTEMS Conforms to OSHA HazCom 2012 Standard and WHMIS 2015 # SAFETY DATA SHEET General Hygiene Advice: Use good industrial hygiene practices and wear recommended personal protection. Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. ## 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES Storage: Keep out of the reach of children. Store locked up. Keep container tightly closed. Store at room temperature and keep containers closed when not in use. ## Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ## 8.1 CONTROL PARAMETER Exposure Guidelines <table><tr><th colspan="3">Occupational Exposure Limits</th></tr><tr><td>Chemical Name</td><td>OSHA-PEL</td><td>ACGIH-TLV</td></tr><tr><td>Trimethoxy vinylsilane</td><td>Not Available</td><td>Not Available</td></tr><tr><td>Amino alkoxysilane</td><td>Not Available</td><td>Not Available</td></tr><tr><td>Crystalline Silica, Quartz*</td><td>0.05 mg/m3</td><td>0.025 mg/m3 (Resp.)</td></tr><tr><td>Methanol (Reaction By-Product)</td><td>260 mg/m³ (200 ppm)</td><td>200 ppm</td></tr></table> *Inhalation of particulates unlikely due to product's physical state. ## 8.2 EXPOSURE CONTROLS Engineering Controls: Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. ## 8.3 INDIVIDUAL PROTECTION MEASURES - 8.3a. Personal Protective Equipment: i. Eye/Face Protection: Wear approved eye protection [properly fitted dust- or splash-proof chemical safety goggles/face (face shield)] - ii.Skin Protection: 1. Hand Protection: Wear impervious gloves, such as nitrile. 2. Body Protection: Wear suitable protective clothing. iii. Respiratory Protection: A NIOSH approved respirator or filtering face piece, such as N95, is recommended in poorly ventilated areas or when permissible exposure limits may b

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